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Carbonized wood serves as the \u201cprimary veins\u201d, providing a 3D conductive framework and mechanical support. Carbon nanotube network acts as the \u201csecondary veins\u201d, accelerating charge transport and mass diffusion. MoO\n                    <jats:sub>x<\/jats:sub>\n                    optimizes the electronic structure of NiCoP and synergizes with the hierarchical structure to enhance the accessibility of active sites and reaction kinetics. The electrode exhibits excellent performances in hydrogen evolution reaction (HER) and urea oxidation reaction (UOR), with potentials of 252\u00a0mV and 1.33\u00a0V at 100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , respectively. In situ electrochemical impedance spectroscopy reveals the indirect oxidation mechanism of UOR and its superior reaction kinetics compared to OER, as well as the Volmer\u2010Heyrovsky mechanism of HER. In the HER||UOR coupled system, the cell voltage at 100 mA\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    was only 1.36\u00a0V, which is 244\u00a0mV lower than that of conventional water electrolysis, while demonstrating high Faradaic efficiency (98.7%) and long\u2010term stability (over 310\u00a0h). This work presents a biomimetic strategy that combines electronic\u2010structure regulation with hierarchical transport frameworks, opening a new avenue for low\u2010energy\u2010consumption hydrogen production and the resource\u2010efficient utilization of urea.\n                  <\/jats:p>","DOI":"10.1002\/smll.76095","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T08:46:35Z","timestamp":1791276395000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Leaf\u2010Vein\u2010Inspired Mo\u2010Modulated NiCoP@CNT\/CW Electrodes for Efficient Urea\u2010Assisted Hydrogen Production"],"prefix":"10.1002","author":[{"given":"Hewei","family":"Hou","sequence":"first","affiliation":[{"name":"Guangxi Key Laboratory of Clean Pulp &amp; Papermaking and Pollution Control School of Light Industry and Food Engineering Guangxi University  Nanning 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