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However, conventional programming stimuli\u2014light and heat\u2014individually exhibit inherent limitations in fabricating geometrically complex, high\u2010fidelity architectures. Herein, we develop a novel poly(disulfide)\u2010based LCE (PDS\u2010LCE) synthesized via end\u2010capping of liquid crystalline oligomers with 1,2\u2010dithiolane, followed by crosslinking through ring\u2010opening polymerization. Leveraging the dual thermo\u2010 and photo\u2010responsiveness of the poly(disulfide) segments, the resulting material can be programmed using either stimulus. Thermo\u2010programming ensures robust and uniform alignment over large areas, whereas photo\u2010programming provides high spatial resolution, remote, and noncontact patterning with localized precision. By synergistically integrating these two complementary approaches, we achieve sophisticated, reconfigurable, and hierarchically structured LCEs that are unattainable by single\u2010stimulus programming. Moreover, the dynamic poly(disulfide) network endows the material with self\u2010healing capability and closed\u2010loop recyclability. We further demonstrate functional soft robotic applications, including self\u2010sustained oscillation and light\u2010guided directional locomotion. This work establishes a versatile platform for designing recyclable and structurally programmable LCEs with advanced functionalities for future soft robotics and adaptive systems.<\/jats:p>","DOI":"10.1002\/smll.76110","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T10:49:09Z","timestamp":1791370149000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Patternable Shape\u2010Morphing and Actuation Enabled by Coupling Photo\u2010 and Thermo\u2010Programming of Poly(Disulfide)\u2010Based Liquid Crystalline Elastomers"],"prefix":"10.1002","author":[{"given":"Jinhua","family":"Su","sequence":"first","affiliation":[{"name":"State Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of China  Hefei Anhui China"},{"name":"Department of Polymer Science and Engineering University of Science and Technology of China  Hefei Anhui 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