{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T11:51:05Z","timestamp":1791373865490,"version":"4.3.1"},"reference-count":54,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T00:00:00Z","timestamp":1791331200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T00:00:00Z","timestamp":1791331200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012334","name":"Graduate Scientific Research and Innovation Foundation of Chongqing","doi-asserted-by":"publisher","award":["CYB25053"],"award-info":[{"award-number":["CYB25053"]}],"id":[{"id":"10.13039\/501100012334","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Rechargeable magnesium batteries (RMBs) are greatly hindered by critical issues in ether and ether\u2010nitrogen co\u2010solvent electrolytes, such as Mg anode passivation, large overpotential, poor thermal stability, and flammability. Herein, we design a deep eutectic electrolyte (DEE, DMSA) consisting of dimethylimidazole (DMIm), Mg(TFSI)\n                    <jats:sub>2,<\/jats:sub>\n                    and 2\u2010methoxyethylamine (MEA) in a molar ratio of 16:1:3. The dual role of the MEA additive synergistically involves the cleavage of the excessively strong DMIm\u2013Mg\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    solvation structure and the reconfiguration of the robust DMIm\u2010TFSI\n                    <jats:sup>\u2212<\/jats:sup>\n                    hydrogen\u2010bonding network. Through imidazole\u2010amine coordination competition and a synergistic hydrogen\u2010bonding network, the solvation structure is reconstructed with a reduced Mg desolvation barrier. Meanwhile, the in situ MgF\n                    <jats:sub>2<\/jats:sub>\n                    \u2010rich organic\/inorganic bilayered SEI ensures the interfacial stability and cycling lifespan. In particular, the inorganic layer portion of MgF\n                    <jats:sub>2<\/jats:sub>\n                    \u2010rich, effectively enhances the stability of the SEI layer at high temperatures. The optimal DEE features intrinsic flame retardancy, a broad operating temperature range (10\u201380\u00b0C), and an ultra\u2010low overpotential of 35\u00a0mV. Astoundingly, the Mg||Mg cell runs stably for 400\u00a0h at 80\u00b0C. Impressively, the Mg||Mo\n                    <jats:sub>6<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    cell realizes long cycling over 1000 cycles even at 5 C at 25\u00b0C and 150 cycles at 60\u00b0C. This work establishes a new solvation design principle that fundamentally resolves the long\u2010standing incompatibility between Mg and non\u2010aqueous eutectic electrolytes, unlocking high\u2010performance, high\u2010temperature RMBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.76114","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T11:03:11Z","timestamp":1791370991000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Imidazole\u2010Amine Synergistic Coordination Reconstructs H\u2010Bonds and Interface Engineering for Mg Metal Batteries at 60\u00b0C"],"prefix":"10.1002","author":[{"given":"Zhihong","family":"Cui","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Chongqing University  Chongqing People's Republic of 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