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Here, we report a transport\u2010engineered Au nanoporous metal film (Au NPMF)\u2010integrated tin dioxide (SnO\n                    <jats:sub>2<\/jats:sub>\n                    ) hybrid structure (Au NPMF@SnO\n                    <jats:sub>2<\/jats:sub>\n                    ) that reverses the native sensing preference of SnO\n                    <jats:sub>2<\/jats:sub>\n                    at room temperature. A continuous Au NPMF is conformally integrated with glancing\u2010angle\u2010deposited SnO\n                    <jats:sub>2<\/jats:sub>\n                    nanorods through a plasma\u2010assisted dry process, producing a permeable metal\/oxide interface while preserving the structural and chemical identity of the oxide scaffold. The Au NPMF does not merely function as a catalytic decoration, but as an interconnected transport\u2010regulating overlayer that modulates gas access, adsorption, and release before molecules reach the SnO\n                    <jats:sub>2<\/jats:sub>\n                    surface. Consequently, the intrinsic NO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010dominant behavior of pristine SnO\n                    <jats:sub>2<\/jats:sub>\n                    is switched to H\n                    <jats:sub>2<\/jats:sub>\n                    S\u2010selective sensing, with improved H\n                    <jats:sub>2<\/jats:sub>\n                    S recovery, stable cycling performance, and a theoretical detection limit of 0.0087\u00a0ppm. This behavior is primarily associated with the continuous nanoporous Au architecture, which couples morphology\u2010controlled gas accessibility with gas\u2010specific adsorption\u2013desorption behavior and interfacial electronic interactions. These findings establish nanoporous metal overlayers as programmable interfacial layers for room\u2010temperature selectivity control in metal oxide gas sensors.\n                  <\/jats:p>","DOI":"10.1002\/smll.76126","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T16:09:13Z","timestamp":1791475753000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Room\u2010Temperature Selectivity Switching via Nanoporous Au Film\u2010Integrated SnO\n                    <sub>2<\/sub>\n                    Hybrid Sensors"],"prefix":"10.1002","author":[{"given":"Yeon\u2010Ju","family":"Ryu","sequence":"first","affiliation":[{"name":"Electronic and Hybrid Materials Research Center Korea Institute of Science and Technology  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2719-7547","authenticated-orcid":false,"given":"Jinwook","family":"Lee","sequence":"additional","affiliation":[{"name":"SKKU Advanced Institute of Nanotechnology Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5517-2630","authenticated-orcid":false,"given":"Jung\u2010Won","family":"An","sequence":"additional","affiliation":[{"name":"Electronic and Hybrid Materials Research Center Korea Institute of Science and Technology  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0685-7991","authenticated-orcid":false,"given":"Soo Young","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6553-9388","authenticated-orcid":false,"given":"Hwayeon","family":"Kum","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology  Daejoen Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3844-8789","authenticated-orcid":false,"given":"Jihan","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology  Daejoen Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-1002","authenticated-orcid":false,"given":"Hyunah","family":"Kwon","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Dong\u2010A University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6018-7231","authenticated-orcid":false,"given":"Ji\u2010Soo","family":"Jang","sequence":"additional","affiliation":[{"name":"SKKU Advanced Institute of Nanotechnology Sungkyunkwan University  Suwon Republic of Korea"},{"name":"Department of Nanoengineering Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","first-page":"11302","DOI":"10.1039\/D5CS00979K","article-title":"Chemiresistive Gas Sensors for Intelligent Sensing: Design Strategies, Emerging Applications and Future Challenges","volume":"54","author":"Hu C.","year":"2025","journal-title":"Chemical Society Reviews"},{"key":"e_1_2_9_3_1","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1038\/s41746-025-01851-4","article-title":"Artificially Intelligent Nasal Perception for Rapid Sepsis Diagnostics","volume":"8","author":"Shin J.","year":"2025","journal-title":"npj Digital Medicine"},{"key":"e_1_2_9_4_1","doi-asserted-by":"crossref","DOI":"10.1002\/smll.202512547","article-title":"Chemiresistive Gas Sensors: Materials, Mechanisms, and Applications on the Road to Intelligence and Multifunctionality","volume":"22","author":"Wang J.","year":"2026","journal-title":"Small"},{"key":"e_1_2_9_5_1","doi-asserted-by":"crossref","DOI":"10.1002\/sstr.202500292","article-title":"Ultrafast Photothermal\u2010Shock\u2010Driven Multimetallic Exsolution for Artificial Olfaction of Sulfur Compounds Detection","volume":"6","author":"Kim G. 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