{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T16:46:36Z","timestamp":1791737196379,"version":"4.3.4"},"reference-count":43,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52301282"],"award-info":[{"award-number":["52301282"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013317","name":"Shanxi Provincial Key Research and Development Project","doi-asserted-by":"publisher","award":["202502060302013"],"award-info":[{"award-number":["202502060302013"]}],"id":[{"id":"10.13039\/501100013317","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Aqueous Zn\u2013S batteries offer high theoretical energy density and intrinsic safety, but iodine\u2010mediated sulfur conversion introduces severe chemical and electrochemical instability at Zn anode. Herein, life\u2010cycle\u2010resolved three\u2010electrode measurements reveal that, although sulfur utilization gradually decreases, the rapid growth of Zn anode polarization and eventual internal short circuit dominate terminal cell failure. Guided by this failure diagnosis, iodoacetamide (IAM) is introduced as a multifunctional additive to couple interphase and solvation regulation. Interfacial spectroscopy and depth profiling indicate the in situ formation of a gradient interphase comprising an N\u2010containing organic\u2010rich outer region and a ZnS\/ZnSO\n                    <jats:sub>3<\/jats:sub>\n                    \u2010rich inorganic inner region, which suppresses polyiodide corrosion and homogenizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux. Spectroscopic analyses and molecular simulations further show that IAM modulates the local Zn\n                    <jats:sup>2+<\/jats:sup>\n                    coordination environment and water hydrogen\u2010bond network, accompanied by enhanced ion pairing and a lower apparent interfacial activation barrier for Zn deposition. As a result, Zn||Cu cells achieve over 2000 cycles with an average coulombic efficiency of 99.91%, while full Zn\u2013S cells retain 484.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 550 cycles at 20 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , corresponding to 75.95% capacity retention (27.26% without IAM). This work highlights the need to balance iodine\u2010enabled sulfur conversion with Zn stability, offering a practical design principle for durable aqueous Zn\u2013S batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.76154","type":"journal-article","created":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T16:10:38Z","timestamp":1791735038000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Failure\u2010Guided Coupling of Interphase and Solvation Chemistry for Durable Aqueous Zn\u2013S Batteries"],"prefix":"10.1002","author":[{"given":"Jiajun","family":"Chen","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Taiyuan University of Technology  Taiyuan People's Republic of 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