{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T16:46:50Z","timestamp":1791737210132,"version":"4.3.4"},"reference-count":54,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T00:00:00Z","timestamp":1791676800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/Y036948\/1"],"award-info":[{"award-number":["EP\/Y036948\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009708","name":"Novo Nordisk Fonden","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009708","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Polymetallic clusters of Fe\n                    <jats:sup>III<\/jats:sup>\n                    constructed without organic bridging ligands are an emerging class of molecules with structures akin to iron oxide minerals, possessing large spin ground states and\/or displaying spin frustration effects. All previous examples, [Fe\n                    <jats:sub>8<\/jats:sub>\n                    ], [Fe\n                    <jats:sub>17<\/jats:sub>\n                    ], [Fe\n                    <jats:sub>30<\/jats:sub>\n                    ] and [Fe\n                    <jats:sub>34<\/jats:sub>\n                    ], have been isolated from pyridine or analogous heterocyclic amine solvents. Here, we report the isolation of an [Fe\n                    <jats:sub>16<\/jats:sub>\n                    ] cluster from dmf. The complex is \u2018isostructural\u2019 with the previously reported [Fe\n                    <jats:sub>17<\/jats:sub>\n                    ] molecular metal oxide, but with the central, tetrahedral Fe\n                    <jats:sup>III<\/jats:sup>\n                    ion absent. Antiferromagnetic exchange interactions between the tetrahedral and octahedral Fe\n                    <jats:sup>III<\/jats:sup>\n                    ions in [Fe\n                    <jats:sub>16<\/jats:sub>\n                    ] lead to a spin ground state of\n                    <jats:italic>S<\/jats:italic>\n                    \u00a0=\u00a020, the highest yet for this family of materials, consistent with the\n                    <jats:italic>S<\/jats:italic>\n                    \u00a0=\u00a035\/2 found for [Fe\n                    <jats:sub>17<\/jats:sub>\n                    ] containing an additional (antiferromagnetically coupled)\n                    <jats:italic>s<\/jats:italic>\n                    \u00a0=\u00a05\/2 ion. Dissolution of [Fe\n                    <jats:sub>16<\/jats:sub>\n                    ] in pyridine regenerates [Fe\n                    <jats:sub>17<\/jats:sub>\n                    ] or the larger [Fe\n                    <jats:sub>30<\/jats:sub>\n                    ], depending on reaction conditions, demonstrating for the first time that these species can be interconverted.\n                  <\/jats:p>","DOI":"10.1002\/smll.76177","type":"journal-article","created":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T16:16:50Z","timestamp":1791735410000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["An \u2018Empty\u2019 [Fe\n                    <sub>16<\/sub>\n                    ] Cage and its Transformation into [Fe\n                    <sub>17<\/sub>\n                    ] and [Fe\n                    <sub>30<\/sub>\n                    ]"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-3181-2218","authenticated-orcid":false,"given":"Annabel J.","family":"MacGregor","sequence":"first","affiliation":[{"name":"EaStCHEM School of Chemistry The University of Edinburgh  Edinburgh Scotland UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8762-1851","authenticated-orcid":false,"given":"Lucinda R. B.","family":"Wilson","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry The University of Edinburgh  Edinburgh Scotland UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1597-3679","authenticated-orcid":false,"given":"Gary S.","family":"Nichol","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry The University of Edinburgh  Edinburgh Scotland UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3699-0195","authenticated-orcid":false,"given":"Marc Ubach I","family":"Cervera","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA) CSIC &amp; Universidad de Zaragoza  Zaragoza Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3511-3510","authenticated-orcid":false,"given":"David","family":"Gracia","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA) CSIC &amp; Universidad de Zaragoza  Zaragoza Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6016-0969","authenticated-orcid":false,"given":"Zhonghao","family":"Chang","sequence":"additional","affiliation":[{"name":"Multidisciplinary Unit for Energy Science (MUFENS) Dpto. F\u00edsica de la Materia Condensada University of Seville  Seville Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3028-6815","authenticated-orcid":false,"given":"Victorino","family":"Franco","sequence":"additional","affiliation":[{"name":"Multidisciplinary Unit for Energy Science (MUFENS) Dpto. F\u00edsica de la Materia Condensada University of Seville  Seville Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7831-012X","authenticated-orcid":false,"given":"Scott J.","family":"Dalgarno","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot\u2010Watt University  Edinburgh Scotland UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6906-0296","authenticated-orcid":false,"given":"Lukas B.","family":"Woodcock","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Copenhagen  Copenhagen Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4011-6476","authenticated-orcid":false,"given":"Stergios","family":"Piligkos","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Physik Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8028-9064","authenticated-orcid":false,"given":"Marco","family":"Evangelisti","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA) CSIC &amp; Universidad de Zaragoza  Zaragoza Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0702-2723","authenticated-orcid":false,"given":"J\u00fcrgen","family":"Schnack","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Physik Universit\u00e4t Bielefeld  Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9365-370X","authenticated-orcid":false,"given":"Euan K.","family":"Brechin","sequence":"additional","affiliation":[{"name":"EaStCHEM School of Chemistry The University of Edinburgh  Edinburgh Scotland UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,11]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"crossref","first-page":"5537","DOI":"10.1039\/b805014g","article-title":"Diol\u2010Type Ligands as Central \u2018Players\u2019 in the Chemistry of High\u2010Spin Molecules and Single\u2010Molecule Magnets","volume":"37","author":"Tasiopoulos A. 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