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However, conventional aqueous electrolytes suffer from issues of zinc dendrite growth, hydrogen evolution, and cathode dissolution, leading to low Coulombic efficiency and poor reversibility of the zinc anode. Non\u2010aqueous electrolytes with thermodynamic stability can improve reversibility, but the application is limited by the scarcity of high\u2010performance zinc salts and sluggish electrochemical kinetics. Thus, this work proposes a synergistic anion\u2010solvent engineering strategy by employing zinc borohydride as a multifunctional additive in a stable acetonitrile\u2010triethyl phosphate\u2010tetrahydrofuran (AN\u2010TEP\u2010THF) ternary non\u2010aqueous electrolyte. The BH\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    anions effectively regulate Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation structures and induce uniform Zn deposition to suppress dendrites. Meanwhile, the ternary solvent system ensures superb solubility, ionic conductivity, and chemical stability. Benefiting from the synergistic effect, the symmetric cell achieves long cycling for over 400\u00a0h, and the full cell assembled with a potassium manganese hexacyanoferrate (KMnHCF) cathode exhibits an excellent capacity retention of 82.2% after 2000 cycles at 0.5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The results demonstrate a feasible strategy to stabilize zinc anodes and boost electrochemical performance, providing new insights for developing high\u2010safety rechargeable non\u2010aqueous zinc\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.76192","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T08:44:07Z","timestamp":1791881047000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Anion\u2010Solvent Engineering: Zinc Borohydride as a Multifunctional Additive for Non\u2010Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Xiuying","family":"Jin","sequence":"first","affiliation":[{"name":"Centre For Hydrogenergy College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics  Nanjing Jiangsu 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