{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T07:46:37Z","timestamp":1792050397858,"version":"4.4.0"},"reference-count":42,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001348","name":"Agency for Science, Technology and Research","doi-asserted-by":"publisher","award":["MTC IRG M23M6c0098"],"award-info":[{"award-number":["MTC IRG M23M6c0098"]}],"id":[{"id":"10.13039\/501100001348","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001348","name":"Agency for Science, Technology and Research","doi-asserted-by":"publisher","award":["R25J2IR072"],"award-info":[{"award-number":["R25J2IR072"]}],"id":[{"id":"10.13039\/501100001348","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001475","name":"Nanyang Technological University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001475","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The electrocatalytic hydrogen evolution reaction (HER) is central to sustainable hydrogen production. Platinum (Pt) is widely regarded as the benchmark HER catalyst due to its near\u2010optimal catalytic properties. However, its scarcity and high cost severely constrain scalable deployment. Here, we demonstrate that structure\u2010induced interfacial electrostatic regulation enables platinum\u2010efficient HER while minimizing Pt loading. A one\u2010dimensional nanoensemble composed of Ag nanowires decorated with Pt nanoparticles integrates electronic hybridization, facet\u2010dependent charge accumulation, and directional charge transport to boost HER. The solid PtAgNW (S\u2010PtAgNW) nanoarchitecture containing only 15\u00a0wt.% Pt achieves the lowest overpotential of 290\u00a0mV at an ECSA\u2010normalized current density of 500\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a Tafel slope of 42\u00a0mV\u00a0dec\n                    <jats:sup>\u22121<\/jats:sup>\n                    . It delivers a Pt\u2010normalized hydrogen production rate of \u223c50\u00a0mol\u00a0g\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at \u223c93% Faradaic efficiency, representing a &gt;6\u2010fold enhancement over its hollow counterpart despite the latter possessing higher Pt loading and similar interfacial chemistry. Mechanistic analysis reveals that Ag\u2010to\u2010Pt electronic coupling and facet redistribution toward Ag(111) enhance electron accumulation under bias, strengthening the interfacial electrostatic environment that governs proton\u2010electron coupling. These findings establish interfacial electrostatic regulation, rather than Pt loading or intrinsic catalyst chemistry alone, as an important determinant of efficient HER.\n                  <\/jats:p>","DOI":"10.1002\/smll.76263","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T06:51:34Z","timestamp":1792047094000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Structure\u2010Dependent Interfacial Electrostatic Regulation Enables Platinum\u2010Efficient Hydrogen Evolution in Pt\u2010Ag Bimetallic Nanowires"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-3673-0171","authenticated-orcid":false,"given":"Carice","family":"Chong","sequence":"first","affiliation":[{"name":"Division of Chemistry and Biological Chemistry School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University  Singapore 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Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-2080-2027","authenticated-orcid":false,"given":"Hongjian","family":"Yu","sequence":"additional","affiliation":[{"name":"Jiangsu Provincial Key Laboratory of Green &amp; Functional Materials and Environmental Chemistry College of Chemistry and Materials Yangzhou University  Yangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3660-029X","authenticated-orcid":false,"given":"Yue\u2010e","family":"Miao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials College of Materials Science and Engineering Donghua University  Shanghai People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0823-4111","authenticated-orcid":false,"given":"Hiang 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