{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T20:40:48Z","timestamp":1792356048598,"version":"4.4.0"},"reference-count":75,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T00:00:00Z","timestamp":1792281600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T00:00:00Z","timestamp":1792281600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22474089"],"award-info":[{"award-number":["22474089"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003787","name":"Natural Science Foundation of Hebei Province","doi-asserted-by":"publisher","award":["B2026110006"],"award-info":[{"award-number":["B2026110006"]}],"id":[{"id":"10.13039\/501100003787","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006606","name":"Natural Science Foundation of Tianjin Municipality","doi-asserted-by":"publisher","award":["23JCZDJC00140"],"award-info":[{"award-number":["23JCZDJC00140"]}],"id":[{"id":"10.13039\/501100006606","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Photocatalytic nitrate reduction to ammonia (NO\n                    <jats:sub>3<\/jats:sub>\n                    RR) could alleviate the energy\/environmental burdens associated with Haber\u2010Bosch process, however, still suffers from insufficient visible\u2010light utilization and low ammonia production rate. Herein, we present the first case of photocatalytic NO\n                    <jats:sub>3<\/jats:sub>\n                    RR using a platinum\u2010loaded organic photovoltaic heterojunction nanoparticle (OPV\u2010NP) as photocatalysts. The donor\/acceptor interpenetrating network inner OPV\u2010NPs overcomes the limitation of intrinsically short exciton diffusion length of organic photosensitizers. By delicately tuning the chemical\/topological structure of near\u2010infrared acceptors, the intermolecular packing strength and crystalline ordering are improved greatly, thus driving the more efficient generation\/transport of charge carriers and ammonia production. As a result, the optimized OPV\u2010NPs achieves a first\u2010class photocatalytic ammonia production rate of 6.79\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and excellent operational stability during 40\u00a0h continuous photocatalysis under AM 1.5G simulated sunlight. This work not only highlights the considerable potential of OPV\u2010NPs in photocatalytic NO\n                    <jats:sub>3<\/jats:sub>\n                    RR but also provides valuable insights for rational material design in such a promising photocatalytic system.\n                  <\/jats:p>","DOI":"10.1002\/smll.76303","type":"journal-article","created":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T20:23:51Z","timestamp":1792355031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["High\u2010Performance Nitrate Photoreduction to Ammonia on Organic Photovoltaic Heterojunction Nanoparticles"],"prefix":"10.1002","author":[{"given":"Shinuo","family":"Guo","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liping","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayuan","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Materials for Intelligent Sensing &amp; Key Laboratory of Organic Integrated Circuits Ministry of Education &amp; Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of Chemistry School of Science Tianjin University  Tianjin China"},{"name":"Zhongguancun Academy  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingqi","family":"Bi","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry &amp; The Centre of Nanoscale Science and Technology &amp; Key Laboratory of Functional Polymer Materials &amp; Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenkai","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering National Institute for Adv. Mater. Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guancheng","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tengshuo","family":"Hou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuying","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1826-3736","authenticated-orcid":false,"given":"Guankui","family":"Long","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering National Institute for Adv. 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Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7626-0026","authenticated-orcid":false,"given":"Yi","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1384-183X","authenticated-orcid":false,"given":"Zhaoyang","family":"Yao","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento\u2010Organic Chemistry &amp; The Centre of Nanoscale Science and Technology &amp; Key Laboratory of Functional Polymer Materials &amp; Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3139-5637","authenticated-orcid":false,"given":"Yaxiao","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials School of Chemistry Tiangong University  Tianjin China"},{"name":"Cangzhou Institute of Tiangong University  Cangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,18]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202103909","article-title":"Challenges and Opportunities for Renewable Ammonia Production via Plasmon\u2010Assisted Photocatalysis","volume":"12","author":"Pu\u00e9rtolas B.","year":"2022","journal-title":"Advanced Energy Materials"},{"key":"e_1_2_8_3_1","doi-asserted-by":"crossref","first-page":"331","DOI":"10.1039\/C9EE02873K","article-title":"Current and Future Role of Haber\u2013Bosch Ammonia in a Carbon\u2010Free Energy Landscape","volume":"13","author":"Smith C.","year":"2020","journal-title":"Energy & Environmental Science"},{"key":"e_1_2_8_4_1","doi-asserted-by":"crossref","first-page":"142","DOI":"10.1016\/j.joule.2019.10.006","article-title":"An Electrochemical Haber\u2010Bosch Process","volume":"4","author":"Kyriakou V.","year":"2020","journal-title":"Joule"},{"key":"e_1_2_8_5_1","doi-asserted-by":"crossref","DOI":"10.1126\/science.aar6611","article-title":"Beyond Fossil Fuel\u2013Driven Nitrogen Transformations","volume":"360","author":"Chen J. 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