{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T21:39:48Z","timestamp":1792359588885,"version":"4.4.0"},"reference-count":212,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T00:00:00Z","timestamp":1792281600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T00:00:00Z","timestamp":1792281600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52271200"],"award-info":[{"award-number":["52271200"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2024A1515010393"],"award-info":[{"award-number":["2024A1515010393"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    With the growing global demand for carbon neutrality and renewable energy technologies, the electrochemical reduction of carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) into high\u2010value fuels and chemicals is regarded as one of the key strategies for achieving carbon recycling. Owing to their distinctive catalytic properties, copper\u2010based materials can effectively promote the selective reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    toward multicarbon (C\n                    <jats:sub>2+<\/jats:sub>\n                    ) products. Hence, copper (Cu)\u2010based materials have attracted extensive research interest in this field. This Review summarizes recent advances in Cu\u2010based catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction toward C\n                    <jats:sub>2+<\/jats:sub>\n                    products from a mechanism\u2010guided perspective. First, the fundamental reaction pathways, C\u2013C coupling mechanisms, thermodynamic and kinetic factors, and dynamic reconstruction of Cu\u2010based catalysts are discussed. Second, the unique characteristics of Cu\u2010based catalysts and representative design strategies for regulating active\u2010site structure, intermediate adsorption, and C\u2013C coupling are highlighted. Representative catalyst systems, including Cu and Cu alloys, Cu\u2010based heterostructures, and compound\u2010derived Cu catalysts, are then discussed with emphasis on their structural features, catalytic performance, and mechanistic insights. Finally, emerging data\u2010driven approaches, practical considerations, current challenges, and future perspectives are discussed, aiming to provide a theoretical basis and technical guidance for the rational design of highly efficient and durable Cu\u2010based CO\n                    <jats:sub>2<\/jats:sub>\n                    RR catalysts.\n                  <\/jats:p>","DOI":"10.1002\/smll.76304","type":"journal-article","created":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T20:49:16Z","timestamp":1792356556000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rational Design of Copper Catalysts for Carbon Dioxide Electroreduction Reaction: Toward Efficient C\u2013C Coupling and C\n                    <sub>2+<\/sub>\n                    Generation"],"prefix":"10.1002","author":[{"given":"Xu","family":"Chen","sequence":"first","affiliation":[{"name":"School of Chemistry and Biological Engineering 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