{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T06:49:48Z","timestamp":1792046988595,"version":"4.4.0"},"reference-count":41,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22125802"],"award-info":[{"award-number":["22125802"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22338001"],"award-info":[{"award-number":["22338001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22478018"],"award-info":[{"award-number":["22478018"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Porous liquids (PLs), which combine permanent porosity with fluidity, represent an emerging class of materials with broad application prospects. The incorporation of catalytic sites into both the porous framework and the liquid medium further enables their use in catalysis. Here, we report a type III porous liquid (PL\u2010Zn\u2010MOF\u201074\u2010DF) fabricated from a functional imidazolium\u2010based ionic liquid (IL1) and defective Zn\u2010MOF\u201074\u2010DF, which exhibits enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    capture capacity and superior performance in the cycloaddition of CO\n                    <jats:sub>2<\/jats:sub>\n                    to epoxides compared to IL1 alone. Under mild conditions (50\u00b0C, 1\u00a0bar), the designed porous liquid boosts the conversion of styrene oxide (SO) by up to 22.6% and that of propylene oxide (PO) by 29.9%. Density Functional Theory (DFT) calculations reveal that the remarkable catalytic enhancement stems from the synergistic interplay between IL1 and the defective metal sites in Zn\u2010MOF\u201074\u2010DF, which facilitates CO\n                    <jats:sub>2<\/jats:sub>\n                    activation and stabilizes key reaction intermediates. This work provides both experimental and theoretical insights into the catalytic mechanism of porous liquids, paving the way for their rational design in sustainable catalysis.\n                  <\/jats:p>","DOI":"10.1002\/smll.76322","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T06:30:46Z","timestamp":1792045846000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Catalysis in Defect\u2010Engineered Zn\u2010MOF\u201074\u2010Based Porous Liquids for Enhanced CO\n                    <sub>2<\/sub>\n                    Cycloaddition Under Mild Conditions"],"prefix":"10.1002","author":[{"given":"Wenyu","family":"Ge","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cun","family":"Chen","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuai","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dagang","family":"Qi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuming","family":"Tu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6436-1399","authenticated-orcid":false,"given":"Zhiyong","family":"Zhou","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chencan","family":"Du","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2571-5702","authenticated-orcid":false,"given":"Zhongqi","family":"Ren","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology  Beijing China"},{"name":"Engineering Research Center of Preparation Technology of Ultra\u2010Pure Chemicals for Integrated Circuit Ministry of Education Beijing University of Chemical 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