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Here, we show a radical\u2010induced structure transformation strategy using persulfates that results in the formation of three new nanoclusters: Au\n                    <jats:sub>41<\/jats:sub>\n                    (SR)\n                    <jats:sub>25<\/jats:sub>\n                    , Au\n                    <jats:sub>46<\/jats:sub>\n                    (SR)\n                    <jats:sub>26<\/jats:sub>\n                    , and Au\n                    <jats:sub>49<\/jats:sub>\n                    (SR)\n                    <jats:sub>27<\/jats:sub>\n                    (SR: thiolate). The double helices of Au\n                    <jats:sub>4<\/jats:sub>\n                    assemblies in their kernel structures are observed to adopt branch and cross\u2010linked growth beyond that of linear growth in the previous FCC\u2010kernelled structure. The superoxide radicals converted from persulfates are revealed to oxidize the Au\n                    <jats:sub>44<\/jats:sub>\n                    precursors with a concurrent Au\u2012S cleavage, leading to the formation of thermodynamically stable nanoclusters, which are confirmed by theoretical calculations and experimental results. This study unveils new perspectives on the reactivity of atomically precise NCs and highlights a radical\u2010based strategy to design more kernel packing structures.\n                  <\/jats:p>","DOI":"10.1002\/smll.76339","type":"journal-article","created":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T19:42:17Z","timestamp":1792698137000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Superoxide Radical Mediated Branch and Crosslink Growth of FCC Kernel in Gold Nanoclusters"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2877-5070","authenticated-orcid":false,"given":"Nan","family":"Xia","sequence":"first","affiliation":[{"name":"Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and Nanotechnology Institute of Solid State Physics HFIPS Chinese Academy of Sciences  Hefei People's Republic of China"},{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-2554-3584","authenticated-orcid":false,"given":"Qing","family":"You","sequence":"additional","affiliation":[{"name":"Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and Nanotechnology Institute of Solid State Physics HFIPS Chinese Academy of Sciences  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongying","family":"Ye","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology Ningbo University  Ningbo People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihao","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and Nanotechnology Institute of Solid State Physics HFIPS Chinese Academy of Sciences  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yajie","family":"Guan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids Ministry of Education College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0651-9562","authenticated-orcid":false,"given":"Wen Wu","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology Ningbo University  Ningbo People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2711-3860","authenticated-orcid":false,"given":"Zhikun","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Materials Physics Anhui Key Laboratory of Nanomaterials and Nanotechnology Institute of Solid State Physics HFIPS Chinese Academy of Sciences  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,22]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","first-page":"8208","DOI":"10.1021\/acs.chemrev.6b00769","article-title":"Atomically Precise Clusters of Noble Metals: Emerging Link Between Atoms and Nanoparticles","volume":"117","author":"Chakraborty I.","year":"2017","journal-title":"Chemical Reviews"},{"key":"e_1_2_9_3_1","doi-asserted-by":"crossref","first-page":"567","DOI":"10.1021\/acs.chemrev.0c00495","article-title":"Toward Active\u2010Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters With Crystallographic Structures","volume":"121","author":"Jin R.","year":"2021","journal-title":"Chemical Reviews"},{"key":"e_1_2_9_4_1","doi-asserted-by":"crossref","first-page":"372","DOI":"10.1038\/s41578-023-00537-1","article-title":"Understanding Ligand\u2010Protected Noble Metal Nanoclusters at Work","volume":"8","author":"Matus M. 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