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The dihedral angles of the\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010linked BODIPY dimer and the\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010linked BODIPY dimer tend to flatten in the T\n                    <jats:sub>1<\/jats:sub>\n                    state, which is detrimental to the occurrence of the intersystem crossing (ISC). Conversely, the dihedral angle of the\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010linked BODIPY dimer, the\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010linked BODIPY dimer and\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010linked BODIPY dimer is within the range of 125\u00b0\u2013143\u00b0 in the T\n                    <jats:sub>1<\/jats:sub>\n                    state, facilitating ISC and the generation of singlet oxygen. Notably, the transition from S\n                    <jats:sub>1<\/jats:sub>\n                    to S\n                    <jats:sub>0<\/jats:sub>\n                    involving lowest unoccupied molecular orbital to highest occupied molecular orbital with long\u2010wavelength emission and moderate oscillator strength underpins the remarkable long emission peaks observed experimentally for\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010linked BODIPY dimer. Moreover, the apparent SOC matrix enhances the ISC process, resulting in a respectable efficiency in generating singlet oxygen for this dimer. In\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010linked BODIPY,\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010\n                    <jats:italic>meso<\/jats:italic>\n                    \u2010linked BODIPY, and\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010linked BODIPY, the S\n                    <jats:sub>1<\/jats:sub>\n                    \u2192T\n                    <jats:sub>1<\/jats:sub>\n                    process is characterized by a significant charge transfer, specifically transitioning from the\n                    <jats:sup>1<\/jats:sup>\n                    CT state to the\n                    <jats:sup>3<\/jats:sup>\n                    LE state, indicative of a spin\u2010orbit charge transfer ISC (SOCT\u2010ISC) mechanism. The ability to regulate the photosensitivity of BODIPY dimers by adjusting the dihedral angle between the two units in the T\n                    <jats:sub>1<\/jats:sub>\n                    state unveils new avenues for designing high\u2010performance photosensitizers for both therapeutic and imaging applications.\n                  <\/jats:p>","DOI":"10.1002\/smo.20240023","type":"journal-article","created":{"date-parts":[[2024,7,22]],"date-time":"2024-07-22T00:08:18Z","timestamp":1721606898000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["The controllable of BODIPY dimers without installing blocking groups as both fluorescence and singlet oxygen generators"],"prefix":"10.1002","volume":"3","author":[{"given":"Jianfang","family":"Cao","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Ocean and Life Sciences Dalian University of Technology  Panjin 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