{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,3]],"date-time":"2026-11-03T20:01:26Z","timestamp":1793736086247,"version":"4.6.1"},"reference-count":122,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2024,11,24]],"date-time":"2024-11-24T00:00:00Z","timestamp":1732406400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Smart Molecules"],"published-print":{"date-parts":[[2024,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Propylene oxide plays a pivotal role as an organic synthesis intermediate, boasting extensive downstream applications and promising market prospects. Propene epoxidation via molecular oxygen has garnered considerable attention due to its cost\u2010effectiveness, environmental friendliness, ease of operation, and straightforward product separation. This paper provides an in\u2010depth exploration of recent advancements, ranging from nanoparticle to Single\u2010atom catalysts (SACs), in the context of propene epoxidation using molecular oxygen. Conventional nanoparticle catalysts, including those based on Ag, Cu, and other metals, are examined with regard to their contributions to support effects, electron effects, or crystal\u2010plane effects within the mechanistic investigation. Furthermore, emerging SACs (specifically Mo, Cu, and Co) are discussed in terms of synthesis strategies, characterization methods, and mechanism studies. This comprehensive review sheds new light on design strategies, relevant characterizations, and thorough mechanism investigations aimed at fostering the development of efficient catalysts, thereby expediting progress in the industrial implementation of propene epoxidation.<\/jats:p>","DOI":"10.1002\/smo.20240025","type":"journal-article","created":{"date-parts":[[2024,11,24]],"date-time":"2024-11-24T14:13:42Z","timestamp":1732457622000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Propene epoxidation with molecular oxygen: Advancements from nanoparticle to single\u2010atom catalysts"],"prefix":"10.1002","volume":"2","author":[{"given":"Qiuming","family":"He","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Lin","sequence":"additional","affiliation":[{"name":"Max Planck\u2010 Cardiff Centre on the Fundamentals of Heterogeneous Catalysis FUNCAT Cardiff Catalysis Institute School of Chemistry Cardiff University  Cardiff UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Defu","family":"Yin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaohe","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"De","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Norwegian University of Science and Technology  Trondheim Norway"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7299-5690","authenticated-orcid":false,"given":"Xiang","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,24]]},"reference":[{"key":"e_1_2_9_2_1","author":"Baer H.","year":"2012","journal-title":"UEIC"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-34967-2"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.07.020"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00724-9"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c04780"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1006\/jcat.1998.2157"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c03340"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfrep.2021.100524"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00792"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP02892J"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11164-011-0424-6"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1080\/01614940.2015.1041849"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal8100421"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA00753D"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00724D"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2016.11.067"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma12213602"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00839-7"},{"key":"e_1_2_9_20_1","unstructured":"B.Cooker A. M.Gaffney J. D.Jewson A. P.Kahn R.Pitchai US Patent 5 770 746."},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1015484121891"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-006-0029-2"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1185200"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs4009368"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs5004454"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY00567F"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2010.08.022"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b03645"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp055467g"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp809821u"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cy00312g"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.05.006"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2005.06.026"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2012.01.027"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-007-9220-8"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2016.11.001"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12598-015-0500-y"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1023420012352"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2004.06.038"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1023\/B:CATL.0000038583.60473.16"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2018.04.005"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2006.01.023"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2016.08.019"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(16)62539-1"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.623"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8594"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b03749"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah6133"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-00996-3"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36147-2"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2015.08.022"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC09827K"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.10.061"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9517(02)93753-X"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2009.09.017"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2005.10.019"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2006.04.028"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp800927y"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b09621"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b07044"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2010.09.002"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.11.032"},{"key":"e_1_2_9_63_1","first-page":"866","volume":"27","author":"Jin Q.\u2010Wei","year":"2011","journal-title":"Chem. Res. Chin. Univ."},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-019-03006-z"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-009-9430-y"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2014.12.002"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2015.08.026"},{"key":"e_1_2_9_68_1","first-page":"174","volume":"3","author":"Seubsai A.","year":"2011","journal-title":"Chem. Cat. Chem."},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-017-2262-7"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.6b03771"},{"key":"e_1_2_9_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA12559J"},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1166\/jnn.2020.17408"},{"key":"e_1_2_9_73_1","first-page":"27","volume":"77","author":"Long W.","year":"2012","journal-title":"Chem. Plus. Chem."},{"key":"e_1_2_9_74_1","first-page":"1215","volume":"6","author":"Seubsai A.","year":"2014","journal-title":"Chem. Cat. Chem."},{"key":"e_1_2_9_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b07793"},{"key":"e_1_2_9_76_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep05767"},{"key":"e_1_2_9_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c06990"},{"key":"e_1_2_9_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b01333"},{"key":"e_1_2_9_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c04731"},{"key":"e_1_2_9_80_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2023.158177"},{"key":"e_1_2_9_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402374"},{"key":"e_1_2_9_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03882"},{"key":"e_1_2_9_83_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-26257-0"},{"key":"e_1_2_9_84_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2019.105897"},{"key":"e_1_2_9_85_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-006-0098-7"},{"key":"e_1_2_9_86_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2006.08.029"},{"key":"e_1_2_9_87_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2014.10.015"},{"key":"e_1_2_9_88_1","first-page":"876","volume":"6","author":"Pang Y.","year":"2014","journal-title":"Chem. Cat. Chem."},{"key":"e_1_2_9_89_1","first-page":"2071","volume":"1","author":"Dai Z.","year":"2016","journal-title":"Chemistry. Select"},{"key":"e_1_2_9_90_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.03.004"},{"key":"e_1_2_9_91_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2014.11.023"},{"key":"e_1_2_9_92_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4NJ01770F"},{"key":"e_1_2_9_93_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11164-017-3058-5"},{"key":"e_1_2_9_94_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.11.029"},{"key":"e_1_2_9_95_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2011.12.059"},{"key":"e_1_2_9_96_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2018.04.103"},{"key":"e_1_2_9_97_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2019.02.001"},{"key":"e_1_2_9_98_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2017.03.031"},{"key":"e_1_2_9_99_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-021-3479-8"},{"key":"e_1_2_9_100_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139940"},{"key":"e_1_2_9_101_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11380"},{"key":"e_1_2_9_102_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04711"},{"key":"e_1_2_9_103_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2023.106183"},{"key":"e_1_2_9_104_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122384"},{"key":"e_1_2_9_105_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.09.024"},{"key":"e_1_2_9_106_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY02526B"},{"key":"e_1_2_9_107_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs500606g"},{"key":"e_1_2_9_108_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY01479D"},{"key":"e_1_2_9_109_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2019.02.104"},{"key":"e_1_2_9_110_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2019.09.005"},{"key":"e_1_2_9_111_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2022.155063"},{"key":"e_1_2_9_112_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03418"},{"key":"e_1_2_9_113_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402435"},{"key":"e_1_2_9_114_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402435"},{"key":"e_1_2_9_115_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201504538"},{"key":"e_1_2_9_116_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2019.03.072"},{"key":"e_1_2_9_117_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2019.116032"},{"key":"e_1_2_9_118_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c07315"},{"key":"e_1_2_9_119_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY02185K"},{"key":"e_1_2_9_120_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.10.009"},{"key":"e_1_2_9_121_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201701139"},{"key":"e_1_2_9_122_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00887F"},{"key":"e_1_2_9_123_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104442"}],"container-title":["Smart Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smo.20240025","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,12,20]],"date-time":"2024-12-20T12:24:42Z","timestamp":1734697482000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smo.20240025"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,24]]},"references-count":122,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2024,12]]}},"alternative-id":["10.1002\/smo.20240025"],"URL":"https:\/\/doi.org\/10.1002\/smo.20240025","archive":["Portico"],"relation":{},"ISSN":["2751-4587","2751-4595"],"issn-type":[{"value":"2751-4587","type":"print"},{"value":"2751-4595","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,24]]},"assertion":[{"value":"2024-05-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-10-27","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e20240025"}}