{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T05:04:55Z","timestamp":1790831095883,"version":"4.1.0"},"reference-count":39,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T00:00:00Z","timestamp":1778025600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T00:00:00Z","timestamp":1778025600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Smart Molecules"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Nitrogen\u2010doped carbon (NC) is widely employed as a conductive matrix in Li\u2010S batteries, yet its intrinsic catalytic contribution is often overlooked when combined with metal compounds. Herein, we propose a hierarchical microreactor architecture that integrates conductive and catalytic functions through an intimately coupled Mo\n                    <jats:sub>2<\/jats:sub>\n                    C@NC interface. Density functional theory calculations demonstrate that coupling NC with Mo\n                    <jats:sub>2<\/jats:sub>\n                    C induces pronounced electron redistribution of N atoms, with pyridinic N exhibiting the strongest charge transfer from Mo\n                    <jats:sub>2<\/jats:sub>\n                    C, making the p\u2010band center closest to the Fermi level, thereby endowing superior LiPSs adsorption activity. Guided by this insight, a phase\u2010inversion strategy is employed using pyridinic\u2010N\u2010rich polyacrylonitrile (PAN) and MoO\n                    <jats:sub>3<\/jats:sub>\n                    precursors to construct a cross\u2010linked MoO\n                    <jats:sub>3<\/jats:sub>\n                    @PAN network, which is subsequently transformed into Mo\n                    <jats:sub>2<\/jats:sub>\n                    C@NC microreactors after carbonization. In this structure, Mo\n                    <jats:sub>2<\/jats:sub>\n                    C nanowires are uniformly confined within pyridinic\u2010N\u2010rich carbon shells, forming a zero\u2010distance conductive\u2013catalytic interface that enables efficient electron transfer from Mo\n                    <jats:sub>2<\/jats:sub>\n                    C to NC. This integrated microreactor provides continuous electron pathways, abundant catalytic sites, and unobstructed ion transport, effectively avoiding pore blockage commonly encountered in conventional composite cathodes. Consequently, the Mo\n                    <jats:sub>2<\/jats:sub>\n                    C@NC cathode exhibits high cycling stability over 1000 cycles at 2.0\u00a0C with a low decay rate of 0.052% per cycle. Even at 4.0\u00a0C, it retains 790.6\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for over 400 cycles with only 0.027% fading per cycle.\n                  <\/jats:p>","DOI":"10.1002\/smo2.70051","type":"journal-article","created":{"date-parts":[[2026,5,7]],"date-time":"2026-05-07T04:40:34Z","timestamp":1778128834000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Phase\u2010inversion constructed Mo\n                    <sub>2<\/sub>\n                    C@NC microreactor with optimized pyridinic N p\u2010band center for high\u2010performance Li\u2013S batteries"],"prefix":"10.1002","volume":"4","author":[{"given":"Fangyi","family":"Chu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Helong","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangcun","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuri","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6674-8279","authenticated-orcid":false,"given":"Gaohong","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaobin","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Chemical Engineering Dalian University of Technology  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2224-9523","authenticated-orcid":false,"given":"Xuehua","family":"Ruan","sequence":"additional","affiliation":[{"name":"Department of Energy and Chemical Engineering Panjin Campus Dalian University of Technology  Panjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,6]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402506"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202407986"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202513859"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01223-1"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c04497"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202513418"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2025.111420"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c10913"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.165275"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2025.111140"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202421780"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202510368"},{"key":"e_1_2_7_14_1","volume":"8","author":"Li Z.","year":"2023","journal-title":"Nat. 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