{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T05:00:46Z","timestamp":1790830846741,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T00:00:00Z","timestamp":1785196800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T00:00:00Z","timestamp":1785196800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Smart Molecules"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The development of luminescent thermometers synchronously exhibiting high sensitivity and stability in a wide temperature range poses significant challenges. Herein, a novel {Pb\n                    <jats:sub>6<\/jats:sub>\n                    } wheels based metal\u2010organic framework (MOF) formulated as [Pb(pyIPA)]\u00b71.2H\n                    <jats:sub>2<\/jats:sub>\n                    O (\n                    <jats:bold>Pb\u2010pyIPA,<\/jats:bold>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    pyIPA\u00a0=\u00a04\u2010(pyridin\u20104\u2010yl)isophthalic acid) was synthesized via a solvothermal procedure. The\n                    <jats:bold>Pb\u2010pyIPA<\/jats:bold>\n                    MOF possesses a new (4,4)\u2010connected zeolite\u2010type structure with dynamic nanotubes modified by {Pb\n                    <jats:sub>6<\/jats:sub>\n                    } wheels. It shows intensive green emission with a long lifetime of 180\u00a0ns and maintains 98.5% of its initial emission intensity after immersion in water for 90\u00a0days. By contrast, temperature\u2010dependent photoluminescence explorations demonstrate that the emission intensity and lifetime decreased linearly over the temperature range of 298\u2013423\u00a0K, achieving a maximal thermal quenching of 93%, relative sensitivity (S\n                    <jats:sub>r<\/jats:sub>\n                    ) of 1.03% K\n                    <jats:sup>\u22121<\/jats:sup>\n                    (intensity\u2010based) and 0.97% K\n                    <jats:sup>\u22121<\/jats:sup>\n                    (lifetime\u2010based). These values surpass those of most reported MOFs and commercial inorganic phosphors. Mechanism of high temperature sensitivity was explored by the combination of single crystal X\u2010ray diffraction analysis and density functional theory calculations. The diameter of {Pb\n                    <jats:sub>6<\/jats:sub>\n                    } wheel can be reversibly tuned under the stimulation of external temperature (298\u2013400\u00a0K), leading to a significant decrease in the electron cloud distribution around the {Pb\n                    <jats:sub>6<\/jats:sub>\n                    } wheels. Thus, both the emission intensity and lifetime can be vastly affected by the dynamic structural transformation. In addition, the stability and reusability of\n                    <jats:bold>Pb\u2010pyIPA<\/jats:bold>\n                    were also investigated, which can maintain high sensitivity under reversible temperature variations between 298 and 423\u00a0K for 5 cycles. This study offers a new perspective for balancing the contradiction between high sensitivity and stability of luminescent thermometers in a wide operational temperature range.\n                  <\/jats:p>","DOI":"10.1002\/smo2.70086","type":"journal-article","created":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T05:06:41Z","timestamp":1785301601000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Novel {Pb\n                    <sub>6<\/sub>\n                    } wheels based zeolite\u2010type metal\u2010organic framework for wide temperature range and high sensitivity of luminescent thermometer"],"prefix":"10.1002","volume":"4","author":[{"given":"Yi\u2010Na","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science &amp; Engineering Xi'an Polytechnic University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Xi'an Polytechnic University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun\u2010Long","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Xi'an Polytechnic University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0690-0355","authenticated-orcid":false,"given":"Xiao\u2010Gang","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Luoyang Normal University  Luoyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1113-5301","authenticated-orcid":false,"given":"Yang\u2010Tian","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Materials Science &amp; Engineering Xi'an Polytechnic University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guo\u2010Ping","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Materials Science Northwest University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao\u2010Yu","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Materials Science Northwest University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,28]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC05022B"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32894-w"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c02644"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2025.05.401"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2025.181107"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC04355C"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CP00099D"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC03357D"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503588"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00660J"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smo.20240002"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/smo.20240066"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00778D"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c01852"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC04228J"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC03330E"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI02588H"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00251A"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03080H"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC03221G"},{"key":"e_1_2_8_22_1","volume":"31","author":"Liu Q. 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