{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T11:50:27Z","timestamp":1791460227757,"version":"4.3.4"},"reference-count":83,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Smart Molecules"],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Odd\u2013even conductance alternation in alkanethiol (CnT, \u201312) self\u2010assembled monolayers has been debated for two decades, with conflicting reports on trends, metal dependence, and microscopic origin. Using conducting probe atomic force microscopy (CP\u2010AFM) with Ag, Au, and Pt electrodes, we extract low\u2010bias conductance  and effective molecule\u2013electrode coupling  via the off\u2010resonant single\u2010level model, combined with rigorous \u2010score statistics (Welch's \u2010test for unequal variances). We present a Solomonic resolution\u2014meaning a balanced compromise that recognizes truth on both sides\u2014to these long\u2010standing controversies. First, the odd\u2013even effect has a dual origin, manifesting in both the contact conductance prefactor (, ) and the length\u2010decay constant (, ). Interface and bulk contributions are therefore not mutually exclusive. The assignment to interface versus bulk remains inferential from transport parameters; independent structural characterization would be desirable but faces substantial experimental challenges. Second, the relative conductance of odd versus even chains reverses with length: odd chains are more conductive at short lengths, while even chains become superior beyond a crossover. A point estimate near \u201313 emerges from the global fits, yet the limited experimental window (\u201312) and the small difference in decay constants produce a wide uncertainty interval; the precise location of the crossover therefore remains undetermined. The qualitative inversion itself (from  to ), however, is a robust finding and offers a natural reconciliation of prior opposing claims. Third, the effect is observed in CP\u2010AFM junctions under the present experimental conditions. Earlier CP\u2010AFM analyses of CnT junctions did not report it because they employed parity\u2010agnostic fitting; once the data are deliberately split by parity the effect becomes statistically clear. Fourth, metal dependence follows parity\u2010insensitive work\u2010function scaling  with . Paradoxically, although absolute odd\u2013even differences are smallest on Ag (conductances \u223c20 times lower than on Au), statistical confidence is highest for Ag (\u2009%), owing to exceptional reproducibility of even\u2010chain data. This analysis demonstrates that \u201cweaker\u201d does not imply \u201cabsent\u201d and highlights the necessity of variance\u2010aware statistics. Apparently contradictory literature findings arise from different regimes of a single underlying phenomenon.<\/jats:p>","DOI":"10.1002\/smo2.70108","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T10:56:12Z","timestamp":1791456972000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Odd\u2010even effects in molecular junctions: A Solomonic resolution of conflicting reports on conductance trends, metal specificity, and microscopic origin"],"prefix":"10.1002","author":[{"given":"Jiajun","family":"Feng","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Materials and Technologies for Energy Conversion, Department of Materials Science and Engineering Guangdong Technion\u2010Israel Institute of Technology  Shantou Guangdong China"},{"name":"Schulich Faculty of Chemistry Technion\u2013Israel Institute of Technology  Haifa Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4860-5757","authenticated-orcid":false,"given":"Ioan","family":"B\u00e2ldea","sequence":"additional","affiliation":[{"name":"Theoretical Chemistry Heidelberg University  Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1828-0122","authenticated-orcid":false,"given":"Zuoti","family":"Xie","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Materials and Technologies for Energy Conversion, Department of Materials Science and Engineering Guangdong Technion\u2010Israel Institute of Technology  Shantou Guangdong China"},{"name":"Quantum Science Center of Guangdong\u2010Hong Kong\u2010Macao Greater Bay Area Shenzhen\u2010Hong Kong International Science and Technology Park  Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1007\/BF01339530","volume":"70","author":"H\u00fcckel E.","year":"1931","journal-title":"Z. 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