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However, flexible wearable electronics require supercapacitors not only with excellent flexibility but also with high energy density. P\u2010diaminoazobenzene (P\u2010Azo) as a new type of organic electrode material with N\uf8feN is directly connected to the benzene ring and forms a large \u03c0\u2010conjugated system, which makes it have a lower lowest unoccupied molecular orbital (LUMO) energy level, is beneficial to transfer of electrons, and increases the conductivity of organic molecules. In addition, N\uf8feN can realize the transfer of two electrons, which makes P\u2010Azo have a higher energy density. Asymmetric flexible supercapacitors are fabricated by assembling P\u2010Azo, activated carbon, and an adhesive electrolyte, with 425.2\u2009mW\u2009h\u2009cm<jats:sup>\u22122<\/jats:sup> (55.19\u2009Wh\u2009kg<jats:sup>\u22121<\/jats:sup>) energy density at a power density of 80\u2009mW\u2009cm<jats:sup>\u22122<\/jats:sup> (10.38\u2009W\u2009kg<jats:sup>\u22121<\/jats:sup>), and 90.7% capacitance retention after 80\u2009000 cycles of bending. In this work, supercapacitors and perovskite submodules are coupled to prepare a photo\u2010rechargeable supercapacitor to achieve a 7% overall energy\u2010conversion efficiency. Therefore, this supercapacitor paves a practical route for powering future wearable electronics.<\/jats:p><\/jats:sec>","DOI":"10.1002\/smsc.202200101","type":"journal-article","created":{"date-parts":[[2023,3,9]],"date-time":"2023-03-09T12:45:14Z","timestamp":1678365914000},"source":"Crossref","is-referenced-by-count":14,"title":["An Azo\u2010Based Electrode for All\u2010Around High\u2010Performance Flexible Supercapacitors"],"prefix":"10.1002","volume":"3","author":[{"given":"Haoxiang","family":"Zhang","sequence":"first","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian Liaoning 116023 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minyong","family":"Du","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean 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