{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T09:11:22Z","timestamp":1789204282745,"version":"build-2803163510"},"reference-count":71,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2023,10,26]],"date-time":"2023-10-26T00:00:00Z","timestamp":1698278400000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2023,10,26]],"date-time":"2023-10-26T00:00:00Z","timestamp":1698278400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["DP180103861"],"award-info":[{"award-number":["DP180103861"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["IH170100009"],"award-info":[{"award-number":["IH170100009"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["DP220102851"],"award-info":[{"award-number":["DP220102851"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Small Science"],"published-print":{"date-parts":[[2023,12]]},"abstract":"<jats:p>\nSingle\u2010atom catalysts (SACs) composed of atomically dispersed metal\u2010active sites embedded in supporting substrates are attracting increasing attention in liquid\u2010phase selective oxidation reactions with joint merits of both advanced catalytic efficiency and high stability. Co\u2010based SACs present superior performance in several model oxidative reactions against many other metals, thus they are recognized as a promising solution to the current high\u2010cost noble\u2010metal catalysts required for the synthesis of fine chemicals. In this review, the up\u2010to\u2010date research on the synthesized Co\u2013SACs in selective oxidation applications is summarized. The strategies of the preparation of Co\u2013SACs with diverse Co\u2010loading levels and well\u2010tuned morphologies and chemical structures are showcased, as well as the characterization techniques of the SACs. The applications of Co\u2013SACs in a series of selective oxidation reactions and the influence of different oxidants on the overall reaction efficiency are discussed. In addition, the progress of the mechanism exploration involving active\u2010site identification, catalytic activation of oxidants, and oxidation pathway elucidation is highlighted. Meanwhile, the existing challenges and the future efforts for the development of the Co\u2013SAC reaction system in selective oxidation processes are outlined.<\/jats:p>","DOI":"10.1002\/smsc.202300079","type":"journal-article","created":{"date-parts":[[2023,10,27]],"date-time":"2023-10-27T02:45:21Z","timestamp":1698374721000},"source":"Crossref","is-referenced-by-count":10,"title":["Advances of Single\u2010Atomic Cobalt Catalysts in Liquid\u2010Phase Selective Oxidative Reactions"],"prefix":"10.1002","volume":"3","author":[{"given":"Jiaquan","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemical and Biomolecular Engineering Sydney Nano Institute The University of Sydney  Sydney NSW 2037 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Wang","sequence":"additional","affiliation":[{"name":"WA School of Mines: Minerals, Energy and Chemical Engineering Curtin University  Perth WA 6102 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yijiao","family":"Jiang","sequence":"additional","affiliation":[{"name":"Department of Engineering Macquarie University  Sydney NSW 2109 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemical and Biomolecular Engineering Sydney Nano Institute The University of Sydney  Sydney NSW 2037 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5019-5182","authenticated-orcid":false,"given":"Shaomin","family":"Liu","sequence":"additional","affiliation":[{"name":"WA School of Mines: Minerals, Energy and Chemical Engineering Curtin University  Perth WA 6102 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,10,26]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60282f"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5458.1636"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00246a049"},{"key":"e_1_2_9_3_3","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01814"},{"key":"e_1_2_9_3_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2015.02.008"},{"key":"e_1_2_9_3_5","doi-asserted-by":"publisher","DOI":"10.1021\/ja3117203"},{"key":"e_1_2_9_3_6","doi-asserted-by":"publisher","DOI":"10.1039\/b301963b"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC00406K"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2GC36441G"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00501"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b04217"},{"key":"e_1_2_9_5_3","doi-asserted-by":"publisher","DOI":"10.1021\/ar300361m"},{"key":"e_1_2_9_5_4","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202300010"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1095"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0063-z"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwy094"},{"key":"e_1_2_9_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202200036"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201701343"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300905"},{"key":"e_1_2_9_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209644"},{"key":"e_1_2_9_8_4","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2022.05.009"},{"key":"e_1_2_9_8_5","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207941"},{"key":"e_1_2_9_8_6","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4196-7"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwy077"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA01940A"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702534"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601364"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2013.03.044"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.117767"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114951"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803262"},{"key":"e_1_2_9_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202100046"},{"key":"e_1_2_9_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202200059"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-018-0010-1"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-01259-z"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/srep01775"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b13100"},{"key":"e_1_2_9_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/am.2017.212"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-022-4556-3"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf5251"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2019.06.012"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.134089"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.0c02141"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.0c06086"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202000026"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201700696"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP01113H"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.0c07794"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-020-3244-4"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NH00036D"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201906437"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC05975J"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA11503G"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004125"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202004579"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.06.062"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-019-0116-5"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201802167"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA10506A"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c23079"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00835a101"},{"key":"e_1_2_9_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)90402-2"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2017.06.018"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202200592"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120877"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b07082"},{"key":"e_1_2_9_44_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.coche.2021.100757"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05273"},{"key":"e_1_2_9_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1NR03157K"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-019-0518-7"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004929"}],"container-title":["Small Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smsc.202300079","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smsc.202300079","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,21]],"date-time":"2024-01-21T09:22:07Z","timestamp":1705828927000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smsc.202300079"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,10,26]]},"references-count":71,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2023,12]]}},"alternative-id":["10.1002\/smsc.202300079"],"URL":"https:\/\/doi.org\/10.1002\/smsc.202300079","archive":["Portico"],"relation":{},"ISSN":["2688-4046","2688-4046"],"issn-type":[{"value":"2688-4046","type":"print"},{"value":"2688-4046","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,10,26]]},"article-number":"2300079"}}