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Herein the soft self\u2010assembly of\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010shaped\n                    <jats:italic>p<\/jats:italic>\n                    \u2010terphenyl\u2010based bolapolyphiles having two adjacent aliphatic side chains at the central benzene ring (catechol dialkyl ethers) is reported with a focus on the design of single\u2010network structures. Depending on the length of the side chains and temperature a series of polygonal honeycombs, a zeolite\u2010like LC, a lamellar phase, and two segmented network phases with cubic symmetry is found. In these networks self\u2010assembled glycerol spheres, forming the junctions, are interconnected by coaxial\n                    <jats:italic>p<\/jats:italic>\n                    \u2010terphenyl bundles. Upon side\u2010chain elongation, a double\u2010gyroid phase with three\u2010way junctions is replaced by the single diamond having a four\u2010way junction network. However, the single gyroid supposed to be formed by further side\u2010chain expansion could not be observed; instead, the LC self\u2010assembly breaks down completely. It is hypothesized that the formation of single\u2010network phases by bottom\u2010up self\u2010assembly in soft matter systems requires a minimum junction valence of at least 4 to stabilize the networks.\n                  <\/jats:p>","DOI":"10.1002\/smsc.202500157","type":"journal-article","created":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T00:34:58Z","timestamp":1747960498000},"source":"Crossref","is-referenced-by-count":8,"title":["From Columns to Networks: Search toward the Elusive Single Gyroid with\n                    <i>\u03c0<\/i>\n                    \u2010Shaped Polyphilic Liquid Crystalline Block Molecules"],"prefix":"10.1002","volume":"5","author":[{"given":"Silvio","family":"Poppe","sequence":"first","affiliation":[{"name":"Institute of Chemistry Martin\u2010Luther\u2010University Halle\u2010Wittenberg  Kurt\u2010Mothes\u2010Stra\u00dfe 2 06120 Halle Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changlong","family":"Chen","sequence":"additional","affiliation":[{"name":"Shaanxi International Research Center for Soft Matter State Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University  Xi'an 710049 P. 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