{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T11:35:38Z","timestamp":1790422538485,"version":"4.1.0"},"reference-count":141,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,8,20]],"date-time":"2025-08-20T00:00:00Z","timestamp":1755648000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Small Science"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:p>\n                    Recent breakthroughs and achievements in the studies of 2D materials have led to the increased attention to the respective van der Waals parent compounds. Herein, the class of layered materials\u2014so\u2010called transition metal phosphorus trichalcogenides (MPX\n                    <jats:sub>3<\/jats:sub>\n                    ; M: transition metal, X: chalcogen)\u2014has been recently investigated extensively due to the diversity in their properties depending on the M\/X combination. Moreover, further studies demonstrate the large tunability of the electronic, optical, and magnetic properties of these materials using different methods, like defects\u2019 engineering, alloying, adsorption, or intercalation. In the present review, several discussed approaches are focused on, highlighting the mechanisms leading to the properties\u2019 modifications and drawing perspectives on the further studies and developments in this class of materials.\n                  <\/jats:p>","DOI":"10.1002\/smsc.202500307","type":"journal-article","created":{"date-parts":[[2025,8,20]],"date-time":"2025-08-20T10:41:34Z","timestamp":1755686494000},"source":"Crossref","is-referenced-by-count":11,"title":["Beyond Pristine Layers: Engineering van der Waals MPX\n                    <sub>3<\/sub>\n                    Materials (M: Transition Metal, X: Chalcogen) via Defects, Adsorption, and Intercalation"],"prefix":"10.1002","volume":"5","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7904-2892","authenticated-orcid":false,"given":"Yuriy","family":"Dedkov","sequence":"first","affiliation":[{"name":"Center for Advanced Laser Techniques Institute of Physics  Bijeni\u010dka cesta 46 10000 Zagreb 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