{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T16:10:27Z","timestamp":1786119027717,"version":"build-2736575974"},"reference-count":60,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T00:00:00Z","timestamp":1775779200000},"content-version":"vor","delay-in-days":9,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T00:00:00Z","timestamp":1775001600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Small Science"],"published-print":{"date-parts":[[2026,4]]},"abstract":"<jats:p>\n                    Electrochemical ethanol oxidation (EOR) is promising strategy for value\u2010added chemical production, such as acetic acid, while replacing energy intensive oxygen evolution reaction at the anode. However, developing efficient, affordable electrocatalysts is crucial for practical ethanol electrolysis to enhance the EOR kinetics, reduce overpotential, and minimize energy losses. In this context, we synthesized a nickel\u2010cobalt\u2010based metal\u2010organic framework (NiCo\u2013MOF) as a precatalyst for ethanol oxidation. The NiCo oxyhydroxides were formed by the in situ reconstruction of the MOF during the cycling process. This reconstructed composite exhibits outstanding electrocatalytic performance toward EOR, achieving a current density of 10\u2009mA\/cm\n                    <jats:sup>2<\/jats:sup>\n                    at 1.33\u2009V (RHE). The reconstructed NiCo\u2013MOF showed a maximum FE of\u2009\u223c95.6% for acetate production at 50\u2009mA\/cm\n                    <jats:sup>2<\/jats:sup>\n                    current density. The better catalytic activity of reconstructed NiCo\u2013MOF compared to other samples is due to its strong synergistic interaction between Ni and Co, which facilitates the preoxidation, thereby increasing the EOR. The catalyst also possesses a stable ethanol electrolysis through 50\u2009h. The overall ethanol electrolysis on the catalyst needs 220\u2009mv less potential compared to water electrolysis at 10\u2009mA\/cm\n                    <jats:sup>2<\/jats:sup>\n                    current density. The result suggests that in situ reconstructed bimetallic MOF could be an efficient electrocatalyst for alcohol electrooxidation for potential green energy integration.\n                  <\/jats:p>","DOI":"10.1002\/smsc.70248","type":"journal-article","created":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T17:44:38Z","timestamp":1775843078000},"source":"Crossref","is-referenced-by-count":1,"title":["In Situ Reconstruction of NiCo\u2013MOF Enhances Acetate Production Through Ethanol Electro\u2010Oxidation in Alkaline Medium"],"prefix":"10.1002","volume":"6","author":[{"given":"Yash Kumar","family":"Yadav","sequence":"first","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anshika","family":"Sahu","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biplab Kumar","family":"Manna","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anirudha","family":"Shekhawat","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajib","family":"Samanta","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sudip","family":"Barman","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER)  Bhubaneswar Orissa India"},{"name":"Homi Bhabha National Institute  Mumbai Maharashtra India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,10]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4834"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100246c"},{"key":"e_1_2_10_4_1","first-page":"1","volume-title":"Advanced Nanomaterials and Their Applications in Renewable Energy","author":"Liu J. 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