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Here we summarize recent advances in MOFs as functional electronic materials, including their use as low\u2010 and high\u2010dielectric\u2010constant insulators, semiconductors with enhanced charge transport, and intrinsic broadband white\u2010light emitters. Key strategies for bandgap and property modulation, such as metal\u2010node selection, \u03c0\u2010conjugated linker design, guest incorporation, and the role of coordinated or confined water, are critically discussed. Recent progress in electrically driven, phosphor\u2010free white\u2010light\u2010emitting MOFs, especially single\u2010component systems, is highlighted as a promising route toward simplified device architectures and environmentally sustainable alternatives to conventional luminescent materials. Remaining challenges in electrical conductivity, operational stability, and scalable device integration are assessed, alongside emerging solutions involving framework dimensionality control, improved charge transport pathways, and predictive computational modeling. 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