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Although amphiphilic micelles are widely used to host molecular cargo, their intrinsic encapsulation capability remains underexplored for directly confining functional molecules within inorganic or hybrid architectures. Here, we report a hierarchical nanocontainer integrating micelle\u2010assisted molecular encapsulation, ZIF\u20108 confinement, and SiO\n                    <jats:sub>2<\/jats:sub>\n                    interfacial engineering for smart self\u2010healing corrosion protection. Amphiphilic P123 micelles first encapsulate benzotriazole (BTA) in situ and direct ZIF\u20108 framework growth around the loaded micelles, enabling efficient one\u2010pot inhibitor confinement without a separate post\u2010loading step. A subsequent SiO\n                    <jats:sub>2<\/jats:sub>\n                    shell improves structural robustness and compatibility with environmentally friendly waterborne polyurethane (WBPU) while preserving pH\u2010responsive release. Under corrosive conditions, local pH changes trigger BTA release, enabling active inhibition and self\u2010healing at damaged sites. The nanocontainers achieve inhibitor loadings up to 16.2\u2009wt% and pH\u2010dependent release, reaching\u2009~35% at pH 3 and\u2009~32% at pH 10, compared with\u2009~4% at pH 7. Incorporated into WBPU coatings, the composite maintains\u2009~1.4\u2009\u00d7\u200910\n                    <jats:sup>7<\/jats:sup>\n                    \u2009\u03a9\u00b7cm\n                    <jats:sup>2<\/jats:sup>\n                    after 39 days in 3.5\u2009wt% NaCl. It also shows a corrosion current density of 3.2\u2009\u00d7\u200910\n                    <jats:sup>\u22129<\/jats:sup>\n                    \u2009A\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and a corrosion rate of 0.0000372\u2009mm year\n                    <jats:sup>\u22121<\/jats:sup>\n                    , demonstrating durable protection. This strategy enables high\u2010loading, release\u2010regulated nanocontainers for anticorrosion coatings.\n                  <\/jats:p>","DOI":"10.1002\/smsc.70367","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T11:21:21Z","timestamp":1787397681000},"source":"Crossref","is-referenced-by-count":0,"title":["Micelle\u2010Assisted Encapsulation Strategy in Metal\u2010Organic Framework Nanocontainers Enables Durable Corrosion Protection"],"prefix":"10.1002","volume":"6","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3172-4629","authenticated-orcid":false,"given":"Asep Sugih","family":"Nugraha","sequence":"first","affiliation":[{"name":"Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kwang Keat","family":"Leong","sequence":"additional","affiliation":[{"name":"Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7854-927X","authenticated-orcid":false,"given":"Yusuke","family":"Yamauchi","sequence":"additional","affiliation":[{"name":"Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Ma","sequence":"additional","affiliation":[{"name":"Baoshan Iron &amp; Steel Co. 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