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Representative NCs include alkynyl\u2010protected [Ag\n                    <jats:sub>25<\/jats:sub>\n                    Cu\n                    <jats:sub>4<\/jats:sub>\n                    (PhC\uf8fdC)\n                    <jats:sub>12<\/jats:sub>\n                    (PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>12<\/jats:sub>\n                    Cl\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    ]\n                    <jats:sup>3+<\/jats:sup>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    ), thiolate\u2010capped [AuCu\n                    <jats:sub>14<\/jats:sub>\n                    (SR)\n                    <jats:sub>12<\/jats:sub>\n                    (PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    (R = 4\u2010flurothiophenol) (\n                    <jats:bold>2<\/jats:bold>\n                    ), and phosphine\u2010stabilized [Au\n                    <jats:sub>9<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    (PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>8<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    (\n                    <jats:bold>3<\/jats:bold>\n                    ), which are fully characterized by single\u2010crystal X\u2010ray diffraction analysis, electrospray ionization mass, nuclear magnetic resonance (\n                    <jats:sup>1<\/jats:sup>\n                    H,\n                    <jats:sup>2<\/jats:sup>\n                    H,\n                    <jats:sup>13<\/jats:sup>\n                    C, and\n                    <jats:sup>31<\/jats:sup>\n                    P NMR), and optical measurements, respectively. This work demonstrates the advantages of using (PPh\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    CuBH\n                    <jats:sub>4<\/jats:sub>\n                    as a reducing agent in the synthesis of Cu\u2010containing heterometallic NCs in terms of versatility as well as high yield and high purity of the products. This work may open the door to utilizing functional metal borohydride, as a new generation of reducing agent for the simple and selective synthesis of metal NCs.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202000603","type":"journal-article","created":{"date-parts":[[2020,9,30]],"date-time":"2020-09-30T02:38:35Z","timestamp":1601433515000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["Simple and Selective Synthesis of Copper\u2010Containing Metal Nanoclusters Using (PPh\n                    <sub>3<\/sub>\n                    )\n                    <sub>2<\/sub>\n                    CuBH\n                    <sub>4<\/sub>\n                    as Reducing Agent"],"prefix":"10.1002","volume":"5","author":[{"given":"Hui","family":"Shen","sequence":"first","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying\u2010Zi","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingyuan","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boon K.","family":"Teo","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9879-4790","authenticated-orcid":false,"given":"Nanfeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials, and National and Local Joint Engineering Research Center for Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 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