{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,21]],"date-time":"2026-02-21T05:24:20Z","timestamp":1771651460113,"version":"3.50.1"},"reference-count":45,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2022,9,8]],"date-time":"2022-09-08T00:00:00Z","timestamp":1662595200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small Methods"],"published-print":{"date-parts":[[2022,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Here, three types of surface coatings based on adsorption of organic aromatic acids or their Li salts are applied as functional coating substrates to engineer the surface properties of high voltage LiNi<jats:sub>0.5<\/jats:sub>Mn<jats:sub>1.5<\/jats:sub>O<jats:sub>4<\/jats:sub> (LNMO) spinel cathodes. The materials used as coating include 1,3,5\u2010benzene\u2010tricarboxylic acid (trimesic acid [TMA]), its Li\u2010salt, and 1,4\u2010benzene\u2010dicarboxylic acid (terephthalic acid). The surface coating involves simple ethanol liquid\u2010phase mixing and low\u2010temperature heat treatment under nitrogen flow. In typical comparative studies, TMA\u2010coated (3\u20135%) LNMO cathodes deliver &gt;90% capacity retention after 400 cycles with significantly improved rate performance in Li\u2010coin cells at 30 \u00b0C compared to uncoated material with capacity retention of \u224840%. The cathode coating also prevents the rapid drop in the electrochemical activity of high voltage Li cells at 55 \u00b0C. Studies of high voltage full cells containing TMA coated cathodes versus graphite anodes also demonstrate improved electrochemical behavior, including improved cycling performance and capacity retention, increased rate capabilities, lower voltage hysteresis, and very minor direct current internal resistance evolution. In line with the highly positive effects on the electrochemical performance, it is found that these coatings reduce detrimental transition metal cations dissolution and ensure structural stability during prolonged cycling and thermal stability at elevated temperatures.<\/jats:p>","DOI":"10.1002\/smtd.202200674","type":"journal-article","created":{"date-parts":[[2022,9,8]],"date-time":"2022-09-08T19:16:28Z","timestamp":1662664588000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Stabilizing High\u2010Voltage LiNi<sub>0.5<\/sub>Mn<sub>1.5<\/sub>O<sub>4<\/sub> Cathodes for High Energy Rechargeable Li Batteries by Coating With Organic Aromatic Acids and Their Li Salts"],"prefix":"10.1002","volume":"6","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9661-7037","authenticated-orcid":false,"given":"Sandipan","family":"Maiti","sequence":"first","affiliation":[{"name":"Department of Chemistry and Institute of 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