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Due to its high reliability and efficiency, the electrochemical nitrate reduction reaction (NO\n                    <jats:sub>3<\/jats:sub>\n                    RR) is regarded as the best available option for mitigating excess nitrate in water and wastewater, especially for the removal of trace levels of nitrate. One of the most critical factors in the electrochemical reduction are the catalysts, which directly affect the reaction efficiency of nitrate removal. Iron\u2010based nanocatalysts, which have the advantages of nontoxicity, wide availability, and low cost, have emerged as a promising electrochemical NO\n                    <jats:sub>3<\/jats:sub>\n                    RR material in recent years. This review covers major aspects of iron\u2010based nanocatalysts for electrochemical NO\n                    <jats:sub>3<\/jats:sub>\n                    RR, including synthetic methods, structural design, performance enhancement, electrocatalytic nitrate reduction test, and reduction mechanism. The recent progress of iron\u2010based nanocatalysts for electrochemical NO\n                    <jats:sub>3<\/jats:sub>\n                    RR and the mechanism of functional advantages for modified structures are reviewed from the perspectives of loading, doping, and assembly strategies, in order to realize the conversion from pollutant nitrate to harmless nitrogen or ammonia and other sustainable products. Finally, challenges and future directions for the development of low\u2010cost and highly\u2010efficient iron\u2010based nanocatalysts are explored.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202200790","type":"journal-article","created":{"date-parts":[[2022,9,14]],"date-time":"2022-09-14T14:56:30Z","timestamp":1663167390000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":160,"title":["Iron\u2010Based Nanocatalysts for Electrochemical Nitrate Reduction"],"prefix":"10.1002","volume":"6","author":[{"given":"Chuqi","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingbing","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxia","family":"Luo","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials and State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei\u2010xian","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resources Reuse Tongji University Shanghai 200092 P. 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