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However, conventional synthesis of PCSs heavily relies on solution\u2010based methods that may lead to environmental issues. Herein, an environment\u2010friendly solvent\u2010free method toward the facile and mass production of\n                    <jats:italic>m<\/jats:italic>\n                    \u2010phenylenediamine\u2010formaldehyde (MPF) resin spheres, which can be converted into PCSs after carbonization and activation is reported. An ultrahigh productivity of 25.89\u00a0g in a 100\u2010mL container and an impressive percent yield of 98.89% can be achieved for the MPF resin spheres, which are further converted into carbon spheres with a reasonable yield of 14.5% after carbonization. When employed as the cathode material for aluminum\u2010ion hybrid capacitors, the obtained PCSs afford a double\u2010layer capacity of \u2248200 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , the highest value among reported porous carbon materials for Al\u2010based EES devices. It is anticipated that the solvent\u2010free synthesis method for PCSs developed here may play a significant role in other EES devices, such as magnesium\u2010ion and calcium\u2010ion hybrid capacitors.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202300150","type":"journal-article","created":{"date-parts":[[2023,4,10]],"date-time":"2023-04-10T05:46:00Z","timestamp":1681105560000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Solvent\u2010Free Synthesis of Polymer Spheres and the Activation to Porous Carbon Spheres for Advanced Aluminum\u2010Ion Hybrid Capacitors"],"prefix":"10.1002","volume":"7","author":[{"given":"Shihao","family":"Feng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan 430070 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