{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T12:44:35Z","timestamp":1788266675619,"version":"build-2803163510"},"reference-count":28,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2024,3,10]],"date-time":"2024-03-10T00:00:00Z","timestamp":1710028800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/X014606\/1"],"award-info":[{"award-number":["EP\/X014606\/1"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small Methods"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The crystal structures of four coordination polymers constructed from Sn(II) and polydentate carboxylate ligands are reported. All are prepared under hydrothermal conditions in KOH or LiOH solutions (either water or methanol\u2013water) at 130\u2212180\u00a0\u00b0C and crystallize as small crystals, microns or less in size. Single\u2010crystal structure solution and refinement are performed using synchrotron X\u2010ray diffraction for two materials and using 3D electron diffraction (3DED) for the others. Sn<jats:sub>2<\/jats:sub>(1,3,5\u2010BTC)(OH), where 1,3,5\u2010BTC is benzene\u20101,3,5\u2010tricarboxylate, is a new polymorph of this composition and has a three\u2010dimensionally connected structure with potential for porosity. Sn(H\u20101,3,5\u2010BTC) retains a partially protonated ligand and has a 1D chain structure bound by hydrogen bonding via \u2500COOH groups. Sn(H\u20101,2,4\u2010BTC) contains an isomeric ligand, benzene\u20101,2,4\u2010tricarboxylate, and contains inorganic chains in a layered structure held by hydrogen bonding. Sn<jats:sub>2<\/jats:sub>(DOBDC), where DOBDC is 2,5\u2010dioxido\u2010benzene\u20101,4\u2010dicarboxylate, is a new polymorph for this composition and has a three\u2010dimensionally connected structure where both carboxylate and oxido groups bind to the tin centers to create a dense network with dimers of tin. In all materials, the Sn centers are found in highly asymmetric coordination, as expected for Sn(II). For all materials phase purity of the bulk is confirmed using powder X\u2010ray diffraction, thermogravimetric analysis, and infrared spectroscopy.<\/jats:p>","DOI":"10.1002\/smtd.202301703","type":"journal-article","created":{"date-parts":[[2024,3,10]],"date-time":"2024-03-10T20:09:29Z","timestamp":1710101369000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Polymorphism and Structural Variety in Sn(II) Carboxylate Coordination Polymers Revealed from Structure Solution of Microcrystals"],"prefix":"10.1002","volume":"9","author":[{"given":"Avneet K.","family":"Ramana","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Warwick  Coventry CV4 7AL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5934-0454","authenticated-orcid":false,"given":"Jeremiah P.","family":"Tidey","sequence":"additional","affiliation":[{"name":"Department of Physics University of Warwick  Coventry CV4 7AL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3816-0320","authenticated-orcid":false,"given":"Geraldo M.","family":"de Lima","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Universidade Federal de Minas Gerais  Avenida Ant\u00f4nio Carlos 6627 Belo Horizonte MG CEP 31270\u2010901 Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9706-2774","authenticated-orcid":false,"given":"Richard I.","family":"Walton","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Warwick  Coventry CV4 7AL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,10]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106259"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c05310"},{"key":"e_1_2_8_4_1","volume-title":"Tin Chemistry: Fundamentals, Frontiers, and Applications","author":"Gielen 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