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However, the uncontrolled dendrite growth and water\u2010triggered side reactions seriously plague its practical application. Herein, a cost\u2010effective and green additive, maltodextrin (MD) is presented, to simultaneously guide the smooth Zn deposition and inhibit the occurrence of water\u2010related side reactions. Combing experimental characterizations and theoretical calculations shows that the MD molecules could reconstruct the Helmholtz plane, induces a preferential growth of zinc along the (002) plane, and the optimized regulation of the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    diffusion path and deposition location also results in the formation of fine\u2010grained Zn deposition layers, thereby inhibiting dendrite growth. In addition, MD molecules readily adsorb to the zinc anode surface, which isolates water molecules from direct contact with the zinc metal, reducing hydrogen precipitation reactions and inhibiting the formation of by\u2010products. Consequently, the Zn||Zn symmetric cell with MD achieves ultra\u2010long stable cycles of up to 5430\u00a0h at 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1\u00a0mA h cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and the Cu||Zn asymmetric cell can stable cycle 1000 cycles with an average coulomb efficiency of 99.78%.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202400249","type":"journal-article","created":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T05:56:25Z","timestamp":1713419785000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Maltodextrin as a Commercial\u2010Grade Electrolyte Additive Against Dendrite Formation and Side Reactions for Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"8","author":[{"given":"Weidong","family":"Du","sequence":"first","affiliation":[{"name":"Advanced Materials Institute 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