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The hybrid is formed by self\u2010assembly of zinc(II) 2,3,9,10,16,17,23,24\u2010Octa[(3\u2032,5\u2032\u2010dicarboxy)\u2010phenoxy]phthalocyaninate (ZnPc*) with the solid\u2010supported monolayer of graphene oxide (GO) mediated by zinc acetate metal cluster. Atomic force microscopy, UV\u2013vis and fluorescence spectroscopies confirm that this simple coordination motive in combination with molecular structure of ZnPc* prevents contact quenching of the light\u2010excited triplet state through aromatic stacking with GO particles. Fluorescence probing with Sensor Green and terephthalic acid as specific indicators of active oxygen intermediates shows that the hybrid nanofilm initiates selective singlet oxygen generation under visible light. Direct one\u2010electron oxidation of tetramethylbenzidine (TMB) (1.0\u00d710\n                    <jats:sup>\u22127<\/jats:sup>\n                    \u00a0\n                    <jats:sc>m<\/jats:sc>\n                    ) on the hybrid surface in the presence of 100\u00a0nm silver nanoparticles as plasmonic hot\u2010spots under 450\u2013640\u2010nm light irradiation yields well\u2010resolved resonance Raman spectrum of the oxidized form TMB\n                    <jats:sup>+1<\/jats:sup>\n                    . Using these hybrid nanofilms as visible light platforms for redox reaction of target analytes without additional oxidizing agents, the range of Raman\u2010detectable compounds can be significantly expanded through a rapid ultrasensitive SERS screening of substances currently considered Raman\u2010inactive.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202401420","type":"journal-article","created":{"date-parts":[[2024,12,21]],"date-time":"2024-12-21T01:21:30Z","timestamp":1734744090000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Graphene Oxide\/Zinc Phthalocyanine Selective Singlet Oxygen Visible\u2010Light Nanosensor for Raman\u2010Inactive Compounds"],"prefix":"10.1002","volume":"9","author":[{"given":"Alexandra I.","family":"Zvyagina","sequence":"first","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olga A.","family":"Shiryaeva","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"},{"name":"Faculty of Chemistry Lomonosov Moscow State University  Leninskie Gory, 1\u20133 Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evgenia Yu.","family":"Afonyushkina","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Lomonosov Moscow State University  Leninskie Gory, 1\u20133 Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olesya O.","family":"Kapitanova","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Lomonosov Moscow State University  Leninskie Gory, 1\u20133 Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexey A.","family":"Averin","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ilya D.","family":"Kormschikov","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2192-7134","authenticated-orcid":false,"given":"Alexander G.","family":"Martynov","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2333-4033","authenticated-orcid":false,"given":"Yulia G.","family":"Gorbunova","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"},{"name":"Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences  Leninsky pr., 31 Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3992-0766","authenticated-orcid":false,"given":"Irina A.","family":"Veselova","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Lomonosov Moscow State University  Leninskie Gory, 1\u20133 Moscow 119991 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2934-9284","authenticated-orcid":false,"given":"Maria A.","family":"Kalinina","sequence":"additional","affiliation":[{"name":"Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences  Leninsky pr., 31, building 4 Moscow 119071 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,20]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214304"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1134\/S1061933X22700107"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2019.00179"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.66"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(22)64096-8"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules27206828"},{"key":"e_1_2_8_7_1","first-page":"63","volume":"3","author":"S\u00f6kmen M.","year":"2017","journal-title":"Am. 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