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Photocatalysis experiments demonstrate that the hydrogen evolution rate (HER) of ThTh\u2010CPP (homopolymer of TTT) reach an exceptional 46.4\u00a0mmol\u00a0g\u207b\u00b9\u00a0h\u207b\u00b9 without co\u2010catalysts, surpassing ThPh\u2010CPP (8.26\u00a0mmol\u00a0g\u207b\u00b9\u00a0h\u207b\u00b9, a copolymer of TTT and TPT) and PhPh\u2010CPP (3.06\u00a0mmol\u00a0g\u207b\u00b9\u00a0h\u207b\u00b9, homopolymer of TPT), as well as nearly all similar polymer\u2010based catalysts reported to date, under visible light. The variance in photocatalytic activity is attributed to differences in the linkage units on the triazine ring. Mechanistic analysis, combining experimental and theoretical studies, highlights the potential of engineering the electron\u2010donating ability of the linkage units to enhance photocatalytic hydrogen evolution in triazine\u2010based conjugated polymers.<\/jats:p>","DOI":"10.1002\/smtd.202401744","type":"journal-article","created":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T02:59:27Z","timestamp":1735268367000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Extending Conjugation Lengths of the Linkage Units in Triazine\u2010Based Porous Polymers for Enhanced Photocatalysis"],"prefix":"10.1002","volume":"9","author":[{"given":"Tingting","family":"Hao","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Liaocheng University  Liaocheng 252059 P. R. 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