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These molecules exhibit three distinctive properties concerning their charge distribution: a neutral internal cavity, a positively charged outer surface, and a negatively charged portal carbonyl oxygen atoms. These unique characteristics facilitate the formation of supramolecular frameworks with a range of anions and metal polyanions. The primary focus of this review is on the creation of anion\u2010induced Q[\n                    <jats:italic>n<\/jats:italic>\n                    ]\u2010based supramolecular self\u2010assemblies and exploring their potential applications in metal ion sequestration and release, gas adsorption, as well as the development of fluorescence probes. Additionally, a concise review of current research on anion\u2010induced Q[\n                    <jats:italic>n<\/jats:italic>\n                    ]\u2010based supramolecular compounds is provided, aiming to stimulate future advancements in the field of innovative supramolecular framework materials.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202402186","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T21:59:55Z","timestamp":1741730395000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Recent Advances in the Construction and Application of Anion\u2010Induced Cucurbit[\n                    <i>n<\/i>\n                    ]uril\u2010Based Supramolecular Assemblies via Outer\u2010Surface Interactions"],"prefix":"10.1002","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9781-4638","authenticated-orcid":false,"given":"Feiyang","family":"Tian","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huangshan University  Huangshan Anhui 245041 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruixue","family":"Cheng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huangshan University  Huangshan Anhui 245041 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Chen","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control School of Environmental Science and Engineering Nanjing University of Information Science &amp; Technology  Nanjing 210044 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiang\u2010Lin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Precision Medicine R&amp;D Center Zhuhai Institute of Advanced Technology Chinese Academy of Sciences  Zhuhai Guangdong 519080 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,3]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19053390102"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020118)41:2<275::AID-ANIE275>3.0.CO;2-M"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/80100074"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja993376p"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00414a070"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00529K"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.07.017"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c01755"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1080\/10610278.2016.1178746"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2024.126087"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1088\/1748-605X\/abcf04"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-022-1312-5"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC07687E"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c01444"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.1c04956"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC02788D"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002666"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.12.018"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60261c"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.12.014"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00273C"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/B603088M"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac200476091633"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201902082"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00269"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00011A"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00095B"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja210068f"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano8110916"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.06.007"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11990"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c04457"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00133"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c08337"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwx013"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/378703a0"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(22)64193-7"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c06935"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05879"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-53853-7"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00585-7"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202401082"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.158182"},{"key":"e_1_2_7_44_1","author":"Ili\u0107 N.","year":"2024","journal-title":"Adv. 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