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Here, a sustainable high\u2010entropy catalyst, FeMnCoZnCu@NCNP@CA is reported, comprising MOF\u2010derived multi\u2010metallic nanoparticles confined within a nitrogen\u2010doped carbon matrix and anchored on a 3D cellulose aerogel scaffold. The hybrid is obtained by pyrolyzing a quinary FeMnCoZnCu\u2013NTA MOF precursor. This hierarchical design integrates several key features: high\u2010entropy stabilization to suppress phase segregation, N\u2010doping\u2010driven charge redistribution to enhance conductivity and active\u2010site density and multivalent redox coupling to promote reactive oxygen species generation (SO\n                    <jats:sub>4<\/jats:sub>\n                    \u2022\n                    <jats:sup>\u2212<\/jats:sup>\n                    , \u2022OH,\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ) and accelerate electron transfer. The confined carbon matrix effectively minimizes metal leaching (&lt;0.1\u00a0ppm), while the aerogel macroporosity ensures rapid diffusion and enables &gt;85% catalyst recovery. Under optimal conditions ([Catalyst] = 0.25\u00a0g L\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    , [PMS] = 0.31\u00a0g L\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    , pH = 3), FeMnCoZnCu@NCNP@CA achieves &gt;98% tetracycline degradation within 15\u00a0min, exhibiting a rate constant (k = 0.070 \u00b1 0.013 min\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    ) that is 4.2 times higher than the mono\u2010metallic Fe@NCNP and surpasses di\u2010, tri\u2010 and tetra\u2010metallic analogues. This work highlights MOF\u2010derived high\u2010entropy hybrids as a promising platform for antibiotic remediation through the synergistic integration of multi\u2010metallic entropy, nitrogen doping, structural confinement and biomass aerogel engineering.\n                  <\/jats:p>","DOI":"10.1002\/smtd.202502192","type":"journal-article","created":{"date-parts":[[2025,12,6]],"date-time":"2025-12-06T05:46:29Z","timestamp":1764999989000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["MOF\u2010Derived Entropy\u2010Stabilized Quinary Alloy@Cellulose Aerogel for Ultrafast Tetracycline Degradation via PMS Activation"],"prefix":"10.1002","volume":"10","author":[{"given":"Javaria Khayaban E","family":"Erum","sequence":"first","affiliation":[{"name":"China\u2010Uzbekistan Joint Laboratory on Advanced Porous Materials State Key Laboratory of Bio\u2010based Fiber Materials School of Materials Science and Engineering Zhejiang Sci\u2010Tech University  Hangzhou 310018 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thamraa","family":"Alshahrani","sequence":"additional","affiliation":[{"name":"Department of Physics College of Science Princess Nourah bint Abdulrahman University Riyadh 11671 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaogang","family":"Yang","sequence":"additional","affiliation":[{"name":"China\u2010Uzbekistan Joint Laboratory on Advanced Porous Materials State Key Laboratory of Bio\u2010based Fiber Materials School of Materials Science and Engineering Zhejiang Sci\u2010Tech University  Hangzhou 310018 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9778-4312","authenticated-orcid":false,"given":"Junkuo","family":"Gao","sequence":"additional","affiliation":[{"name":"China\u2010Uzbekistan Joint Laboratory on Advanced Porous Materials State Key Laboratory of Bio\u2010based 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