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Herein, we report a multifunctional Janus fabric (PAM\u2010Textile) engineered by integrating a hydrophobic polyvinylidene fluoride (PVDF) layer with a hydrophilic silver\u2010decorated MXene (Ag@MXene). This asymmetric structure enables highly efficient unidirectional water transport, rapidly drawing sweat away from the skin while preventing reverse flow, thereby maintaining a dry, breathable microenvironment. The PAM\u2010Textile exhibits remarkable wetting contrast: at 0 s, the hydrophobic side shows a water contact angle (WCA) of 120\u00b0, while the hydrophilic side measures only 56\u00b0. Water droplets transfer from hydrophobic to hydrophilic side within 3 s and are completely absorbed within 4 s, evidenced by a rapid drop in WCA from 120\u00b0 to 0\u00b0. Additionally, the fabric demonstrates excellent thermal regulation, with high solar reflectivity (\u223c99.9%) in the wavelength range of 0.3\u20133\u00a0\u00b5m, an emissivity of 94.3% within the atmospheric transparency window of 8\u201320\u00a0\u00b5m, reducing the skin temperature up to \u223c12.1\u00b0C under artificial sunlight and \u223c9.8\u00b0C under direct sunlight. Moreover, the PAM\u2010Textile shows broad\u2010spectrum antibacterial performance against methicillin\u2010resistant Staphylococcus aureus (MRSA), attributed to the synergistic effect of Ag nanoparticles, MXene nanosheets, and PVDF. The fabric also exhibits strong mechanical stability and wash durability, retaining its multifunctional performance after 10 washings and 20 abrasion cycles. This work presents a scalable and high\u2010performance approach to smart textile design, offering a robust platform for next\u2010generation wearable applications in healthcare, sportswear, and personal protective clothing.<\/jats:p>","DOI":"10.1002\/smtd.202502391","type":"journal-article","created":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T06:58:06Z","timestamp":1782802686000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Smart Antibacterial Janus Fabric Based on PVDF\/Ag\u2010Decorated\u2010MXene for Unidirectional Water Transport and Thermal Management"],"prefix":"10.1002","volume":"10","author":[{"given":"Waqas","family":"Ahmad","sequence":"first","affiliation":[{"name":"HEJ Research Institute of Chemistry International Center for Chemical and Biological Sciences University of Karachi  Karachi 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