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In this review, we focus on the elaboration of patchy particles, categorizing the different synthesis strategies based on the specific interfacial environments employed to induce asymmetry. Recent advances, as a function of the various interfacial constraints, are reviewed: (1) solid\u2010gas interfaces, which exploit physical shadowing for directional deposition; (2) liquid\u2013gas interfaces, taking advantage of surface tension and wettability to create tunable dynamic masks for selective modification; (3) solid\u2010liquid interfaces, utilizing surface immobilization to restrict chemical access or induce site\u2010selective growth; and (4) liquid\u2010liquid interfaces, where soft boundaries facilitate symmetry breaking via thermodynamic partitioning, confinement induced assembly, and bipolar electrochemistry. By revealing the relationship between interfacial synthesis conditions, the triggered chemical reactions, and the final particle features, this review aims to provide practical insights and design principles for engineering next\u2010generation\u00a0patchy particles with tailored complexity.<\/jats:p>","DOI":"10.1002\/smtd.70766","type":"journal-article","created":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T10:09:44Z","timestamp":1780999784000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis of Patchy Particles at Phase Boundaries"],"prefix":"10.1002","volume":"10","author":[{"given":"Lin","family":"Zhang","sequence":"first","affiliation":[{"name":"Engineering Research Center for Nanomaterials Henan University  Kaifeng China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Kuhn","sequence":"additional","affiliation":[{"name":"University Bordeaux, CNRS, Bordeaux 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