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Separator design critically regulates the electrode\u2010electrolyte interface, yet conventional approaches often struggle to simultaneously achieve mechanical robustness, efficient ion transport, and effective water activity regulation. Herein, we design a hybrid bacterial cellulose@UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    (BM) separator via in situ growth of UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    within a bacterial cellulose (BC) hydrogel, followed by a final hot\u2010pressing step, which synergistically combines the complementary properties of both components. The BC matrix confines water via hydrogen bonding, suppressing parasitic reactions, while the amino\u2010functionalized MOF opens up ion\u2010transport pathways that sieve and desolvate Zn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    for uniform flux. This design yields a thin (\u223c34\u00a0\u00b5m thick), robust (161.71\u00a0MPa tensile strength), highly porous (71.6%), and ionically conductive (3.53 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) membrane. Consequently, the BM separator enables a stable Zn anode with a long cycling life of over 1000\u00a0h at 2\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    \/2 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in symmetric cells and significantly improved performance in Zn||NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    full cells, retaining 85.32% capacity after 500 cycles at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work presents a strategy integrating mechanical robustness with dual regulation of water state and ion transport for high\u2010performance AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/smtd.70821","type":"journal-article","created":{"date-parts":[[2026,7,6]],"date-time":"2026-07-06T07:03:19Z","timestamp":1783321399000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Regulation of Water Activity and Ion Transport by an In Situ\u2010Grown MOF\/Bacterial Cellulose Separator for High\u2010Performance Zn Anodes"],"prefix":"10.1002","volume":"10","author":[{"given":"Chen","family":"Fu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9258-9785","authenticated-orcid":false,"given":"Suqing","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou P. R. 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