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While interfacial engineering is recognized as a key strategy, a systematic framework to deconstruct and compare the diverse interaction mechanisms across material families is needed. This review addresses this need by analyzing recent progress in MXene composite cathodes through a unique dual\u2010framework perspective, focusing on interfacial bonding strength (weak vs. strong) and spatial integration geometry (surface\u2010confined vs. interlayer\u2010embedded). This approach provides a unified lens to elucidate distinct structure\u2010performance relationships across vanadium\u2010based, manganese\u2010based, and other cathode materials. The analysis clarifies that the deliberate construction of strong chemical coupling at the interface is a decisive factor for achieving superior cycling stability and high\u2010rate capability. More importantly, we further elucidate the evolving roles of MXenes as active hosts and as precursors for MXene\u2010derived cathodes. Finally, the review synthesizes an integrated roadmap, emphasizing the synergistic advancement of interface design, synthesis, characterization, and application to guide the future development of durable and high\u2010performance ARZIBs.<\/jats:p>","DOI":"10.1002\/smtd.70974","type":"journal-article","created":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T06:01:32Z","timestamp":1787032892000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Recent Interface Interactions Engineering in MXene Composite Cathodes for Enhanced Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"10","author":[{"given":"Xiangrong","family":"Cao","sequence":"first","affiliation":[{"name":"School of Physics and Opto\u2010Electronic Technology Baoji University of Arts and Sciences  Baoji Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiao","family":"Yuan","sequence":"additional","affiliation":[{"name":"College of Physics and Electronic Information Engineering Qinghai Normal University  Xining China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9028-6441","authenticated-orcid":false,"given":"Heng","family":"Wu","sequence":"additional","affiliation":[{"name":"Energy Science and Technology Research Institute Xi'an Branch State Power Investment Corporation  Xi'an Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longkai","family":"Pan","sequence":"additional","affiliation":[{"name":"College of Physics and Electronic Information Engineering Qinghai Normal University  Xining China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haiqing","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Physics and Opto\u2010Electronic Technology Baoji University of Arts and Sciences  Baoji Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-0061-1570","authenticated-orcid":false,"given":"Minggang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physics and Opto\u2010Electronic Technology Baoji University of Arts and Sciences  Baoji Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0124-5638","authenticated-orcid":false,"given":"Peng","family":"Chang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Xi'an University of Science and Technology  Xi'an Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yansong","family":"Liu","sequence":"additional","affiliation":[{"name":"Ningbo Institute of NPU Northwestern Polytechnical University  Ningbo Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhong","family":"Zhou","sequence":"additional","affiliation":[{"name":"School of Physics and Opto\u2010Electronic Technology Baoji University of Arts and Sciences  Baoji Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6113-7834","authenticated-orcid":false,"given":"Hui","family":"Mei","sequence":"additional","affiliation":[{"name":"Science and Technology on Thermostructural Composite Materials Laboratory School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,17]]},"reference":[{"key":"e_1_2_11_2_1","unstructured":"T.Andre Renewables 2020 Global Status Report. 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