{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T07:01:48Z","timestamp":1790146908858,"version":"4.0.1"},"reference-count":70,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378426"],"award-info":[{"award-number":["22378426"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22138013"],"award-info":[{"award-number":["22138013"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20245"],"award-info":[{"award-number":["U22A20245"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["25CX02020A"],"award-info":[{"award-number":["25CX02020A"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2022MB088"],"award-info":[{"award-number":["ZR2022MB088"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small Methods"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The practical application of aqueous zinc\u2010ion batteries (AZIBs) is hindered by Zn dendrite growth, water\u2010induced parasitic reactions, and interfacial instability at the Zn anode. Herein, we propose a multifunctional molecular engineering strategy by introducing 2\u2010cyclohexylaminoethanesulfonic acid (CHES), an amphiphilic electrolyte additive containing sulfonic acid, amino, and hydrophobic cyclohexyl groups, to regulate the Zn anode microenvironment. Experimental investigations and theoretical calculations reveal that CHES coordinates with Zn\n                    <jats:sup>2+<\/jats:sup>\n                    to reconstruct the solvation structure, while its multifunctional groups reorganize the hydrogen\u2010bond network and reduce the reactivity of interfacial water, thereby suppressing hydrogen evolution and interfacial corrosion. Meanwhile, CHES molecules preferentially adsorb onto the Zn surface to form a stable molecular protective layer, which homogenizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux, promotes uniform nucleation, and enables compact Zn deposition. The hydrophobic cyclohexyl moiety further provides steric shielding against water attack, enhancing interfacial stability. Consequently, Zn||Zn symmetric cells achieve stable cycling for over 3000\u00a0h at 2\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Moreover, Zn||NVO full cells retain 84% of their capacity after 3000 cycles at 5\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work highlights the importance of multi\u2010site molecular regulation in constructing durable Zn anodes and provides a versatile strategy for advanced aqueous zinc\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/smtd.71057","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T06:20:02Z","timestamp":1790144402000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solvation Chemistry and Interfacial Modulation by Zwitterionic 2\u2010Cyclohexylaminoethanesulfonic Acid for Highly Reversible Aqueous Zinc Batteries"],"prefix":"10.1002","author":[{"given":"Yongjuan","family":"Chen","sequence":"first","affiliation":[{"name":"Shandong Key Laboratory of Advanced Electrochemical Energy Storage Technologies College of New Energy China University of Petroleum (East China)  Qingdao 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