{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T13:07:25Z","timestamp":1790255245447,"version":"4.1.0"},"reference-count":72,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB3809300"],"award-info":[{"award-number":["2023YFB3809300"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373306"],"award-info":[{"award-number":["52373306"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22409154"],"award-info":[{"award-number":["22409154"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004761","name":"Natural Science Foundation of Hainan Province","doi-asserted-by":"publisher","award":["526MS0268"],"award-info":[{"award-number":["526MS0268"]}],"id":[{"id":"10.13039\/501100004761","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004761","name":"Natural Science Foundation of Hainan Province","doi-asserted-by":"publisher","award":["525QN388"],"award-info":[{"award-number":["525QN388"]}],"id":[{"id":"10.13039\/501100004761","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2023AFA053"],"award-info":[{"award-number":["2023AFA053"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2024BAA013"],"award-info":[{"award-number":["2024BAA013"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small Methods"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Direct regeneration can preserve the value of spent lithium iron phosphate (LFP) cathodes, but conventional relithiation and thermal repair remain limited by sluggish solid\u2010state diffusion and incomplete reconstruction of the phosphate framework. A silicon\u2010assisted strategy is introduced to couple olivine\u2010lattice restoration with electronic and interfacial reactivation. Structural characterization and density functional theory calculations support preferential Si\n                    <jats:sup>4+<\/jats:sup>\n                    incorporation at P\u2010deficient sites, which locally expands the lattice, lowers the Li\n                    <jats:sup>+<\/jats:sup>\n                    migration barrier from 0.67 to 0.43\u00a0eV, and narrows the band gap from 3.71 to 1.25\u00a0eV. These changes strengthen Fe\u2010O orbital interactions and accelerate ionic and electronic transport. The regenerated material (Si\u2010RLFP) delivers 150.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2 C, 102.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 C, and 87.12% capacity retention after 500 cycles at 5 C. A preliminary process assessment estimates an energy demand of 3.347\u00a0MJ kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a net profit of $2.22 kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work identifies phosphate\u2010framework reconstruction as a key factor in spent\u2010LFP regeneration and provides a scalable strategy for the high\u2010value and sustainable recycling of LFP cathodes.\n                  <\/jats:p>","DOI":"10.1002\/smtd.71061","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:43:54Z","timestamp":1790253834000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Silicon\u2010Assisted Direct Regeneration of Spent Lithium Iron Phosphate Cathodes via Coupled Lattice and Electronic Reactivation"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-2773-8846","authenticated-orcid":false,"given":"Zhiqiang","family":"Chen","sequence":"first","affiliation":[{"name":"Sanya Science and Education Innovation Park Wuhan University of Technology  Sanya China"},{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longhao","family":"Rao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junjie","family":"Zhou","sequence":"additional","affiliation":[{"name":"Sanya Science and Education Innovation Park Wuhan University of Technology  Sanya China"},{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangwan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Sanya Science and Education Innovation Park Wuhan University of Technology  Sanya China"},{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Huang","sequence":"additional","affiliation":[{"name":"Sanya Science and Education Innovation Park Wuhan University of Technology  Sanya China"},{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuanpeng","family":"Wang","sequence":"additional","affiliation":[{"name":"Sanya Science and Education Innovation Park Wuhan University of Technology  Sanya China"},{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"},{"name":"Zhongyu Feima New Material Technology Innovation Center (Zhengzhou) Co. Ltd  Zhengzhou Henan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2972-8815","authenticated-orcid":false,"given":"Jiashen","family":"Meng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology For Materials Synthesis and Processing Wuhan University of Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.5c08420"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c03520"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5GC01122A"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213168"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147201"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5GC03642A"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202503248"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00362D"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.etran.2025.100531"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/idm2.70024"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2021.229622"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2019.10.017"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.hydromet.2021.105614"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.3390\/pr12091861"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2018.09.013"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b01594"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2020.05.046"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.resconrec.2025.108766"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12613\u2010020\u20102137\u20106"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2025.145306"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.8268985"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2019.04.304"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.167249"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2025.08.065"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202410482"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c20621"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2026.124009"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c05384"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202508112"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104269"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301353"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2025.136071"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202400762"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susmat.2023.e00575"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41596\u2010025\u201001234\u20109"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.161928"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202507117"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c22666"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2026.02.034"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.102312"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75876"},{"key":"e_1_2_8_43_1","first-page":"017","article-title":"Flexible Direct Regeneration of Heterogeneous Cathode Materials of Spent Lithium\u2010ion Batteries at Industrial Scale","volume":"13","author":"Wang J.","year":"2026","journal-title":"National Science Review"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2026.05.004"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14676"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.96.125150"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104645"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121327"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201073780\u2010z"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202521983"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5GC06175J"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D6EE02323A"},{"key":"e_1_2_8_54_1","first-page":"710","volume-title":"The Rietveld Method","author":"Albinati A.","year":"2004"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2024.136553"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01991"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.76162"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010022\u201000915\u20102"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207076"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202502930"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104777"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2026.174208"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.71089"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2026.122007"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0008-6223(96)00095-4"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0121903jes"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945\u20107111\/ab631a"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945\u20107111\/ac3940"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12598\u2010024\u201003007\u2010x"},{"key":"e_1_2_8_70_1","first-page":"2059","article-title":"Pathway Decisions for Reuse and Recycling of Retired Lithium\u2010ion Batteries Considering Economic and Environmental Functions","volume":"44","author":"Ma R.","year":"2024","journal-title":"Nature Communications"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2026.02.022"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5GC02987B"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70390"}],"container-title":["Small Methods"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smtd.71061","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smtd.71061","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smtd.71061","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:43:56Z","timestamp":1790253836000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smtd.71061"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,24]]},"references-count":72,"alternative-id":["10.1002\/smtd.71061"],"URL":"https:\/\/doi.org\/10.1002\/smtd.71061","archive":["Portico"],"relation":{},"ISSN":["2366-9608","2366-9608"],"issn-type":[{"value":"2366-9608","type":"print"},{"value":"2366-9608","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,24]]},"assertion":[{"value":"2026-08-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71061"}}