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Herein, we report a multifunctional molecular bridge strategy utilizing a rationally designed naphthalene diimide derivative, NDI\u2010Me, featuring synergistic methyl and hydroxyl functionalization. Distinct from its analogues (NDI\u2010Ph and NDI\u2010OH), NDI\u2010Me establishes a unique dual hydrogen\u2010bonding network: phenolic hydroxyl groups firmly anchor onto ZnO to passivate surface oxygen vacancies, while simultaneously interacting with fluorine atoms in the photoactive layer to facilitate charge extraction. Coupled with the electron\u2010donating methyl groups, this synergistic interaction effectively reduces the ZnO work function to 4.04\u00a0eV and accelerates active layer crystallization kinetics. Consequently, PBDB\u2010TF:BTP\u2010eC9\u2010based OSCs incorporating ZnO\/NDI\u2010Me deliver a champion PCE of 18.28%. Crucially, the NDI\u2010Me interface effectively suppresses UV\u2010induced photocatalytic degradation, enabling encapsulated devices to retain 88.7% of their initial efficiency after 1800\u00a0h of continuous illumination. This work highlights the potential of hydrogen\u2010bond\u2010mediated molecular bridges in constructing efficient and stable organic photovoltaics.<\/jats:p>","DOI":"10.1002\/smtd.71088","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:51:13Z","timestamp":1791265873000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Dual Hydrogen\u2010Bonding Molecular Bridge Strategy Enables Efficient and Stable Inverted Organic Solar Cells"],"prefix":"10.1002","author":[{"given":"Jiawu","family":"Yu","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou P. R. 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