{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T01:40:38Z","timestamp":1791250838839,"version":"4.1.0"},"reference-count":29,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2010,11,15]],"date-time":"2010-11-15T00:00:00Z","timestamp":1289779200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["The Chemical Record"],"published-print":{"date-parts":[[2010,12,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis and isolation of stable bimetallic complexes that contain formally quintuply bonded transition metals is a novel and emerging field of science. Efforts have been undertaken in designing and tuning the ligands to achieve a very short (actually the shortest) metal\u2010metal bond. The motivation for these efforts arose from the expectation that an increasing bond order may go along with a shortening of the bond length. In consequence, formally quintuply bonded bimetallics could have shorter metal\u2010metal distances than quadruply bonded ones. A chromium homo\u2010bimetallic complex with a Cr\u2010Cr bond length of 1.7293(12) \u00c5 has been synthesized, and a formal bond order of five was assigned. This compound holds the record for the shortest metal\u2010metal bond in a stable molecule to date. At this stage, there is no evidence that additional shortening is impossible. \u00a9 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Published online in Wiley InterScience (<jats:ext-link xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"http:\/\/www.interscience.wiley.com\">www.interscience.wiley.com<\/jats:ext-link>) <jats:bold>DOI 10.1002\/tcr.201000028<\/jats:bold><\/jats:p>","DOI":"10.1002\/tcr.201000028","type":"journal-article","created":{"date-parts":[[2010,11,15]],"date-time":"2010-11-15T09:34:28Z","timestamp":1289813668000},"page":"413-416","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["The shortest metal\u2010metal bond"],"prefix":"10.1002","volume":"10","author":[{"given":"Awal","family":"Noor","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rhett","family":"Kempe","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,11,15]]},"reference":[{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.359"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1007\/b136230"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19643290111"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50185a067"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50186a010"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/254503a0"},{"key":"e_1_2_2_7_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic50171a003"},{"key":"e_1_2_2_8_2","first-page":"654","volume":"36","author":"Yu M.","year":"1974","journal-title":"Opt Spektrosc"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(83)85029-5"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1116789"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja072003i"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0725549"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja076356t"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp808758h"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1021\/ic801537w"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic702112e"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0710860"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801286"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801286"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803859"},{"key":"e_1_2_2_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803859"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801160"},{"key":"e_1_2_2_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801160"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804048"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200900175"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja905035f"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.255"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/b901494b"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-05243-9_3"}],"container-title":["The Chemical Record"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Ftcr.201000028","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/tcr.201000028","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,7]],"date-time":"2023-10-07T10:56:12Z","timestamp":1696676172000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/tcr.201000028"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,11,15]]},"references-count":29,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2010,12,13]]}},"alternative-id":["10.1002\/tcr.201000028"],"URL":"https:\/\/doi.org\/10.1002\/tcr.201000028","archive":["Portico"],"relation":{},"ISSN":["1527-8999","1528-0691"],"issn-type":[{"value":"1527-8999","type":"print"},{"value":"1528-0691","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,11,15]]},"assertion":[{"value":"2010-08-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2010-11-15","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}