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Predictable site\u2010selective C\u2010C bond formation was achieved through activation of the C\u2010H bonds in each coupling partner and the migration of a C\u2010N double bond. Mechanistic studies strongly suggested that the reaction proceeded via an oxonium\/iminium cation species as the key intermediate. The mechanistic information allows for future extension of outer\u2010sphere redox catalysis. <jats:bold>DOI 10.1002\/tcr.201100024<\/jats:bold><\/jats:p>","DOI":"10.1002\/tcr.201100024","type":"journal-article","created":{"date-parts":[[2011,9,6]],"date-time":"2011-09-06T07:33:05Z","timestamp":1315294385000},"page":"236-241","update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Catalytic migratory oxidative coupling of nitrones through an outer\u2010sphere C(<i>sp<sup>3<\/sup><\/i>)\u2010H activation process"],"prefix":"10.1002","volume":"11","author":[{"given":"Shogo","family":"Hashizume","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kounosuke","family":"Oisaki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Motomu","family":"Kanai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2011,9,6]]},"reference":[{"key":"e_1_2_6_2_2","volume-title":"Topics in Current Organic Chemistry","author":"Yu J.\u2010Q.","year":"2010"},{"key":"e_1_2_6_2_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.11.027"},{"key":"e_1_2_6_2_4","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs90010b"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1114731"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1038\/nature06485"},{"key":"e_1_2_6_3_4","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15013h"},{"key":"e_1_2_6_3_5","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00182a"},{"key":"e_1_2_6_3_6","author":"Wencel\u2010Delord J.","year":"2011","journal-title":"Chem. 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