{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:56:36Z","timestamp":1786978596650,"version":"build-2736575974"},"reference-count":42,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2014,8,4]],"date-time":"2014-08-04T00:00:00Z","timestamp":1407110400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["The Chemical Record"],"published-print":{"date-parts":[[2014,10]]},"abstract":"Abstract<\/jats:title>\n \n Molecular interaction on metal surfaces is one of the central issues of surface science for the microscopic understanding of heterogeneous catalysis. In this Personal Account,\n I<\/jats:styled-content>\n review the recent studies on\n NO<\/jats:styled-content>\n \/\n C<\/jats:styled-content>\n u(110) employing a scanning tunneling microscope (\n STM<\/jats:styled-content>\n ) to probe and control the molecule\u2013molecule interaction on the surface. An individual\n NO<\/jats:styled-content>\n molecule was observed as a characteristic dumbbell\u2010shaped protrusion, visualizing the 2\u03c0* orbital. By manipulating the intermolecular distance with the\n STM<\/jats:styled-content>\n , the overlap of the 2\u03c0* orbital between two\n NO<\/jats:styled-content>\n molecules was controlled. The interaction causes the formation of the bonding and antibonding orbitals below and above the Fermi level, respectively, as a function of the intermolecular distance. The 2\u03c0* orbital also plays a role in the reaction of\n NO<\/jats:styled-content>\n with water molecules. A water molecule donates a\n H<\/jats:styled-content>\n \u2010bond to\n NO<\/jats:styled-content>\n , giving rise to the down\u2010shift of the 2\u03c0* level below the Fermi level. This causes electron transfer from the substrate to\n NO<\/jats:styled-content>\n , weakening, and eventually rupturing, the\n N<\/jats:styled-content>\n \u2013\n O<\/jats:styled-content>\n bond. The facile bond cleavage by water molecules has implications for the catalytic reduction of\n NO<\/jats:styled-content>\n under ambient conditions.\n <\/jats:p>","DOI":"10.1002\/tcr.201402029","type":"journal-article","created":{"date-parts":[[2014,8,4]],"date-time":"2014-08-04T08:19:31Z","timestamp":1407140371000},"page":"827-833","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Imaging Molecular Interaction of\n NO<\/scp>\n on\n C<\/scp>\n u(110) with a Scanning Tunneling Microscope"],"prefix":"10.1002","volume":"14","author":[{"given":"Hiroshi","family":"Okuyama","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science Kyoto University Kyoto 606\u20108502 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