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A large number of nanosized heterogeneous catalysts for three\u2010component coupling reactions between an aldehyde, an amine, and a terminal alkyne have been popularly introduced as an A<jats:sup>3<\/jats:sup> coupling in the last decade. The coupling product has found a broad application as a key intermediate for a variety of heterocyclic useful compounds and numerous biologically active molecules such as \u03b2\u2010lactams, conformationally restricted peptides, isosteres, herbicides, fungicides, indolizines, pyrroles, quinolines and therapeutic drug molecules. This review aims to give an overview of the current progress made towards the preparation and application of various nanocatalysts\u2010catalyzed A<jats:sup>3<\/jats:sup> coupling transformations for the synthesis of propargylamines from 2007 to 2017. Several nanocatalysts based on metal and metal oxide nanoparticles (NPs) such as copper, gold, silver, iron, nickel, cobalt and zinc have successfully been employed in A<jats:sup>3<\/jats:sup> coupling reactions. Besides, core\u2010shells NPs, polymers, complexes, graphenes, metal\u2010organic frameworks and ionic liquids have also been used in these reactions. Abundant examples have been given in this area. Different aspects of the reactions, disparate methods of preparation of nanocatalysts, characterization and their reusability have been perused.<\/jats:p>","DOI":"10.1002\/tcr.201700100","type":"journal-article","created":{"date-parts":[[2018,3,15]],"date-time":"2018-03-15T12:14:58Z","timestamp":1521116098000},"page":"1409-1473","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":83,"title":["A Review on Recent Advances in the Application of Nanocatalysts in A<sup>3<\/sup> Coupling Reactions"],"prefix":"10.1002","volume":"18","author":[{"given":"Mahmoud","family":"Nasrollahzadeh","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Qom  Qom 37185-359 Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohaddeseh","family":"Sajjadi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Qom  Qom 37185-359 Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fatemeh","family":"Ghorbannezhad","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science University of Qom  Qom 37185-359 Iran"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S. 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