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Advancing this cyclization with other metals as well as developing new methods around the products that result from this reaction is one aspect that has seen growing interest. On the other hand, the idea of generating \u03b1\u2010oxo gold carbenes <jats:italic>via<\/jats:italic> oxygen transfer to alkynes has established another important aspect in gold\u2010catalysis. In this account, we will be dealing with the first aspect, which revolves around the internal redox cyclization of nitroalkynes (trivially called as nitroalkyne cycloisomerization), focusing mainly on the gold\u2010complexes and the synthetic methods developed around it from our group and from other groups, and also providing the details of similar transformations documented with other metals so that the complementary reactivity\/diversity of these transformations could be appreciated.<\/jats:p>","DOI":"10.1002\/tcr.202100111","type":"journal-article","created":{"date-parts":[[2021,6,2]],"date-time":"2021-06-02T08:54:19Z","timestamp":1622624059000},"page":"3546-3558","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Gold\u2010Catalysed Nitroalkyne Cycloisomerization \u2013 Synthetic Utility"],"prefix":"10.1002","volume":"21","author":[{"given":"Pawan S.","family":"Dhote","sequence":"first","affiliation":[{"name":"Organic Chemistry Division CSIR- National Chemical Laboratory  Dr.Homi Bhabha Road Pune 411008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Swapnil V.","family":"Halnor","sequence":"additional","affiliation":[{"name":"Organic Chemistry Division CSIR- National Chemical Laboratory  Dr.Homi Bhabha Road Pune 411008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5801-311X","authenticated-orcid":false,"given":"Chepuri V.","family":"Ramana","sequence":"additional","affiliation":[{"name":"Organic Chemistry Division CSIR- National Chemical Laboratory  Dr.Homi Bhabha Road Pune 411008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"Selected reviews\/book chapter on gold-catalysed reaction:"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602454"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200602454"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr000436x"},{"key":"e_1_2_7_4_2","first-page":"108","author":"Patil N. 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