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Recent advances in the carbonylative transformations with TFBen (benzene\u20101,3,5\u2010triyl triformate) as a safe and convenient CO precursor are systematically summarized and discussed, which can be divided into three parts based on the patterns of the obtained products. This Review focuses on the discussion of the application of TFBen in carbonylative synthesis of various carbonyl\u2010containing compounds.<\/jats:p>","DOI":"10.1002\/tcr.202100220","type":"journal-article","created":{"date-parts":[[2021,9,30]],"date-time":"2021-09-30T17:39:33Z","timestamp":1633023573000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["TFBen (Benzene\u20101,3,5\u2010triyl triformate): A Powerful and Versatile CO Surrogate"],"prefix":"10.1002","volume":"22","author":[{"given":"Hefei","family":"Yang","sequence":"first","affiliation":[{"name":"Department of Chemistry, Key Laboratory of Surface &amp; Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University  Hangzhou 310018 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Key Laboratory of Surface &amp; Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University  Hangzhou 310018 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengkai","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Key Laboratory of Surface &amp; Interface Science of Polymer Materials of Zhejiang Province Zhejiang Sci-Tech University  Hangzhou 310018 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Feng","family":"Wu","sequence":"additional","affiliation":[{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics, Chinese Academy of Sciences  Dalian 116023, Liaoning People's Republic of China"},{"name":"Leibniz-Institut f\u00fcr Katalyse e.V.  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