{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T19:36:53Z","timestamp":1771961813128,"version":"3.50.1"},"reference-count":105,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2021,10,7]],"date-time":"2021-10-07T00:00:00Z","timestamp":1633564800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["The Chemical Record"],"published-print":{"date-parts":[[2021,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The construction of carbon\u2010fluorine bonds is an important yet challenging task in organic synthesis. Transition metal\u2010catalyzed\/\u2010mediated C\u2212F bond forming processes have recently emerged as a viable strategy and provided access to value\u2010added monofluorinated compounds. A dramatic increase in fluorination methods using inexpensive and earth\u2010abundant copper can be seen in the past decade surpassing those using palladium and silver. This review discusses the recent development of Cu\u2010catalyzed\/\u2010mediated formation of C(sp<jats:sup>2<\/jats:sup>)\u2212F and C(sp<jats:sup>3<\/jats:sup>)\u2212F bonds.<\/jats:p>","DOI":"10.1002\/tcr.202100231","type":"journal-article","created":{"date-parts":[[2021,10,9]],"date-time":"2021-10-09T17:59:22Z","timestamp":1633802362000},"page":"4015-4031","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Construction of Carbon\u2010Fluorine Bonds via Copper\u2010Catalyzed\/\u2010Mediated Fluorination Reactions"],"prefix":"10.1002","volume":"21","author":[{"given":"Tao","family":"Dong","sequence":"first","affiliation":[{"name":"Department of Chemistry The Chinese University of Hong Kong, Shatin  New Territories Hong Kong SAR China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4824-8745","authenticated-orcid":false,"given":"Gavin Chit","family":"Tsui","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Chinese University of Hong Kong, Shatin  New Territories Hong Kong SAR China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,10,7]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201901840"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.7b01788"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2010.03.003"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jfluchem.2014.06.014"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/B610213C"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/B711844A"},{"key":"e_1_2_6_8_1","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cen-v084n033.p015"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1131943"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules26030627"},{"key":"e_1_2_6_12_1","unstructured":"\u00a0"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr4002879"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00392"},{"key":"e_1_2_6_15_1","unstructured":"\u00a0"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00493"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106785"},{"key":"e_1_2_6_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201106785"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0782426"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800222"},{"key":"e_1_2_6_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800222"},{"key":"e_1_2_6_20_1","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/352760393X"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470988589"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC02067B"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC05181J"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00778"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1588489"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00248"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603697"},{"key":"e_1_2_6_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201603697"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002386"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500368h"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500706a"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar4003202"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206566"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206566"},{"key":"e_1_2_6_34_1","unstructured":"\u00a0"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar9001763"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature10108"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/om200507g"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc16158c"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob25702e"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT03410D"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410288"},{"key":"e_1_2_6_41_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201410288"},{"key":"e_1_2_6_42_2","first-page":"612","volume":"115","author":"Campbell M. G.","year":"2015","journal-title":"Chem. Res."},{"key":"e_1_2_6_43_1","unstructured":"A keyword search of \u201cmetal\u201d AND \u201cfluorination\u201d in SCOPUS for 2000\u20132021 has revealed the following numbers of documents found: palladium (342) silver (210) copper (390)."},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527826445"},{"key":"e_1_2_6_45_1","unstructured":"\u00a0"},{"key":"e_1_2_6_46_2","first-page":"4475","volume":"111","author":"Tomashenko O. A.","year":"2011","journal-title":"Chem. Res."},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201200648"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4QO00003J"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40336-020-00368-y"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2058567"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo300152u"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja304410x"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC51876K"},{"key":"e_1_2_6_54_1","unstructured":"\u00a0"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol4025716"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/om5007903"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja310909q"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja400300g"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja408607r"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02125"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201905040"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1076397"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/op700266y"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4047125"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0037-1610130"},{"key":"e_1_2_6_66_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-019-0353-3"},{"key":"e_1_2_6_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02490"},{"key":"e_1_2_6_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2020.152624"},{"key":"e_1_2_6_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b01110"},{"key":"e_1_2_6_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00615"},{"key":"e_1_2_6_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02516"},{"key":"e_1_2_6_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203642"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203642"},{"key":"e_1_2_6_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol102818g"},{"key":"e_1_2_6_74_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB00588F"},{"key":"e_1_2_6_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1OB00144B"},{"key":"e_1_2_6_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007403"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202007403"},{"key":"e_1_2_6_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03044"},{"key":"e_1_2_6_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02238"},{"key":"e_1_2_6_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02239"},{"key":"e_1_2_6_80_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02583"},{"key":"e_1_2_6_81_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301891"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201301891"},{"key":"e_1_2_6_82_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo4010074"},{"key":"e_1_2_6_83_1","doi-asserted-by":"publisher","DOI":"10.1021\/om4008967"},{"key":"e_1_2_6_84_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201402238"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201402238"},{"key":"e_1_2_6_85_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506882"},{"key":"e_1_2_6_85_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506882"},{"key":"e_1_2_6_86_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202001015"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202001015"},{"key":"e_1_2_6_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06770"},{"key":"e_1_2_6_88_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202000081"},{"key":"e_1_2_6_89_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201406797"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201406797"},{"key":"e_1_2_6_90_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC10162F"},{"key":"e_1_2_6_91_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC04909B"},{"key":"e_1_2_6_92_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03077"},{"key":"e_1_2_6_93_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01133"}],"container-title":["The Chemical Record"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/tcr.202100231","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/tcr.202100231","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/tcr.202100231","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T08:02:08Z","timestamp":1693209728000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/tcr.202100231"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,10,7]]},"references-count":105,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2021,12]]}},"alternative-id":["10.1002\/tcr.202100231"],"URL":"https:\/\/doi.org\/10.1002\/tcr.202100231","archive":["Portico"],"relation":{},"ISSN":["1527-8999","1528-0691"],"issn-type":[{"value":"1527-8999","type":"print"},{"value":"1528-0691","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,10,7]]},"assertion":[{"value":"2021-08-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-09-20","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-10-07","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}