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Secondly, pyrrolidine\u2010based secondary\u2010amino aliphatic Tf\u2010amide catalyzed asymmetric direct Mannich reaction. Thirdly, chiral primary\u2010amino aliphatic Tf\u2010amide catalyzed asymmetric direct aldol reaction and conjugate addition. Finally, modified chiral amino aromatic Tf\u2010amide catalyzed asymmetric transformations. These four different strategies are illustrated by using various organocatalyzed asymmetric transformations.<\/jats:p>","DOI":"10.1002\/tcr.202200004","type":"journal-article","created":{"date-parts":[[2022,2,18]],"date-time":"2022-02-18T11:22:50Z","timestamp":1645183370000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Design of Bifunctional Amino Tf\u2010Amide Organocatalysts and Application in Various Asymmetric Transformations"],"prefix":"10.1002","volume":"22","author":[{"given":"Hyo\u2010Jun","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Chemistry Kunsan National University  Gunsan 54150 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0044-6411","authenticated-orcid":false,"given":"Keiji","family":"Maruoka","sequence":"additional","affiliation":[{"name":"Graduate School of Pharmaceutical Sciences Kyoto University 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