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After Chen and White's pioneering works, various non\u2010heme\u2010type iron and manganese complexes were introduced, leading to strong development in this area. However, for this method to become a truly useful tool for synthetic organic chemistry, it is necessary to make further efforts to improve site\u2010selectivity, and catalyst durability. Recently, we found that non\u2010heme\u2010type ruthenium complex <jats:italic>cis<\/jats:italic>\u2010<jats:bold>1<\/jats:bold> presents efficient catalysis in C(sp<jats:sup>3<\/jats:sup>)\u2212H oxygenation under acidic conditions. <jats:italic>cis<\/jats:italic>\u2010<jats:bold>1<\/jats:bold>\u2010catalysed C\u2212H oxygenation can oxidize various substrates including highly complex natural compounds using hypervalent iodine reagents as a terminal oxidant. Moreover, the catalyst system can use almost stoichiometric water molecules as the oxygen source through reversible hydrolysis of PhI(OCOR)<jats:sub>2<\/jats:sub>. 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